Skip to main content
Ch.6 - Electronic Structure of Atoms

Chapter 6, Problem 9a

The contour representation of one of the orbitals for the n = 3 shell of a hydrogen atom is shown here. (a) What is the quantum number l for this orbital?

Verified Solution
Video duration:
3m
This video solution was recommended by our tutors as helpful for the problem above.
447
views
Was this helpful?

Video transcript

Welcome back everyone in this example we need to determine the value of the quantum number. L. For the given representation of an orbital where the orbital lies at the fourth energy level. So this is the representation of our orbital given in the prompt and we should recognize that we have a dumbbell shape that is surrounded buy a ring whenever we have an orbital with the shape described here, we would recall that this is for a D. Orbital. Recall that we can also depict the orbital's as a flower shape. So the orbital's can also be depicted as a flower shape where we have four lobes which intersect one another and form a flower shape here. So this is just a small sketch of how you can also recognize a D. Orbital. But in this case we're given the dumbbell shape surrounded by ring. So we know we have a D. Orbital here and it lies at the fourth energy level according to our prompt. Now we want to recall our facts on quantum numbers and given in the prompt we have a value of N being four which is our energy level here for orbital. And we should recall that and is also known as our principal quantum number. And according to the prompt because we need to find L. Recall that L. Is known as the angular momentum quantum number. Now you can determine the angular momentum quantum number by taking your principle quantum number N. And subtracting it from one which would give you a range of L. Values which in this case would be for N - or sorry for - and that would give us L equal to either values of 01, two or three. However, because we are given specifically the representation of a D orbital, we can say that because we have a D orbital given we can say therefore our value for L is always going to equal for a D orbital the value to and that is because a angular momentum quantum number with a value of two corresponds to a D orbital. And so our final answer to complete this example is going to be that L is equal to two. So what's highlighted in yellow in our solution is our final answer here. If you have any questions, please leave them down below and I will see everyone in the next practice video.
Related Practice
Textbook Question

A certain quantum-mechanical system has the energy levels shown in the accompanying diagram. The energy levels are indexed by a single quantum number n that is an integer. (b) Which quantum numbers are involved in the transition that requires the least energy?

589
views
Textbook Question

Consider the three electronic transitions in a hydrogen atom shown here, labeled A, B, and C. (a) Three electromagnetic waves, all drawn on the same scale, are also shown. Each corresponds to one of the transitions. Which electromagnetic wave (i), (ii), or (iii), is associated with electronic transition C?

1396
views
2
rank
Textbook Question

Consider a fictitious one-dimensional system with one electron. The wave function for the electron, drawn below, is c1x2 = sin x from x = 0 to x = 2p. (b) At what value or values of x will there be the greatest probability of finding the electron?

526
views
Textbook Question

The contour representation of one of the orbitals for the n = 3 shell of a hydrogen atom is shown here. (c) In which of the following ways would you modify this sketch if the value of the magnetic quantum number, ml, were to change? (i) It would be drawn larger, (ii) the number of lobes would change, (iii) the lobes of the orbital would point in a different direction, (iv) there would be no change in the sketch.

209
views
Textbook Question

The accompanying drawing shows a contour plot for a dyz orbital. Consider the quantum numbers that could potentially correspond to this orbital. (b) What is the value of the angular momentum quantum number, l?

487
views
Textbook Question

The accompanying drawing shows a contour plot for a dyz orbital. Consider the quantum numbers that could potentially correspond to this orbital. (c) What is the largest possible value of the magnetic quantum number, ml?

516
views