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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 55a

(a) For n = 4, what are the possible values of l?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Quantum Numbers

Quantum numbers are a set of numerical values that describe the unique quantum state of an electron in an atom. They include the principal quantum number (n), azimuthal quantum number (l), magnetic quantum number (m_l), and spin quantum number (m_s). Each quantum number provides specific information about the electron's energy level, shape, orientation, and spin.
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Principal Quantum Number

Principal Quantum Number (n)

The principal quantum number (n) indicates the main energy level or shell of an electron in an atom. It can take positive integer values (1, 2, 3, ...), with higher values corresponding to electrons that are further from the nucleus and have higher energy. In this case, n = 4 signifies the fourth energy level.
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Principal Quantum Number

Azimuthal Quantum Number (l)

The azimuthal quantum number (l) defines the shape of the electron's orbital and can take on integer values from 0 to (n-1). For n = 4, the possible values of l are 0, 1, 2, and 3, which correspond to the s, p, d, and f orbitals, respectively. This concept is crucial for understanding the distribution of electrons in an atom.
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Magnetic Quantum Number