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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 6b

A certain quantum-mechanical system has the energy levels shown in the accompanying diagram. The energy levels are indexed by a single quantum number n that is an integer. (b) Which quantum numbers are involved in the transition that requires the least energy?
Diagram showing energy levels indexed by quantum number n for quantum mechanics.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Quantum Numbers

Quantum numbers are numerical values that describe the unique quantum state of an electron in an atom. The principal quantum number (n) indicates the energy level of the electron, with higher values corresponding to higher energy levels. In this context, transitions between these levels involve changes in energy, which are quantified by the difference in the principal quantum numbers.
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Energy Transitions

Energy transitions in quantum systems occur when an electron moves between different energy levels. The energy required for a transition is determined by the difference in energy between the initial and final states. The least energy transition corresponds to the smallest difference in quantum numbers, which can be calculated as the absolute difference between the two involved quantum numbers.
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Energy Level Diagram

An energy level diagram visually represents the allowed energy levels of a quantum system, with each level corresponding to a specific quantum number. In the provided diagram, the levels are indexed by n, where n = 1 is the lowest energy state and n = 5 is the highest. Analyzing this diagram helps identify which transitions require the least energy by observing the proximity of the levels.
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Related Practice
Textbook Question

A popular kitchen appliance produces electromagnetic radiation with a frequency of 2450 MHz. With reference to Figure 6.4, answer the following: (d) Which of the following is the appliance likely to be? (i) A toaster oven, (ii) A microwave oven, or (iii) An electric hotplate.

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Textbook Question

Stars do not all have the same temperature. The color of light emitted by stars is characteristic of the light emitted by hot objects. Telescopic photos of three stars are shown below: (i) the Sun, which is classified as a yellow star, (ii) Rigel, in the constellation Orion, which is classified as a blue-white star, and (iii) Betelgeuse, also in Orion, which is classified as a red star. (a) Place these three stars in order of increasing temperature. (i) sun (ii) Rigel (iii) Betelguese

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Textbook Question

The familiar phenomenon of a rainbow results from the diffraction of sunlight through raindrops. (a) Does the wavelength of light increase or decrease as we proceed outward from the innermost band of the rainbow?

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Textbook Question

Consider the three electronic transitions in a hydrogen atom shown here, labeled A, B, and C. (a) Three electromagnetic waves, all drawn on the same scale, are also shown. Each corresponds to one of the transitions. Which electromagnetic wave (i), (ii), or (iii), is associated with electronic transition C?

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Textbook Question

Consider a fictitious one-dimensional system with one electron. The wave function for the electron, drawn below, is c1x2 = sin x from x = 0 to x = 2p. (b) At what value or values of x will there be the greatest probability of finding the electron?

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Textbook Question

The contour representation of one of the orbitals for the n = 3 shell of a hydrogen atom is shown here. (a) What is the quantum number l for this orbital?

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