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Ch.5 - Thermochemistry
Chapter 5, Problem 122

Consider the following acid-neutralization reactions involving the strong base NaOH(aq): HNO31aq2 + NaOH1aq2¡NaNO31aq2 + H2O1l2 HCl1aq2 + NaOH1aq2¡NaCl1aq2 + H2O1l2 NH4+1aq2 + NaOH1aq2¡NH31aq2 + Na+1aq2 + H2O1l2 (d) In the third equation NH4 +1aq2 is acting as an acid. Based on the value of H° for this reaction, do you think it is a strong or a weak acid? Explain.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid-Base Theory

Acid-base theory explains the behavior of acids and bases in chemical reactions. According to the Brønsted-Lowry theory, acids are proton donors, while bases are proton acceptors. In the given reaction, NH4+ acts as an acid by donating a proton to NaOH, forming NH3 and water. Understanding this theory is crucial for identifying the role of substances in acid-base reactions.
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Strength of Acids

The strength of an acid is determined by its ability to dissociate in solution and release protons (H+ ions). Strong acids, like HCl and HNO3, completely dissociate in water, while weak acids, like NH4+, only partially dissociate. The degree of dissociation can be inferred from the reaction's enthalpy change (ΔH°), which indicates whether the reaction is favorable and how readily the acid donates protons.
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Enthalpy Change (ΔH°)

Enthalpy change (ΔH°) is a measure of the heat absorbed or released during a chemical reaction at constant pressure. A negative ΔH° indicates that the reaction is exothermic, suggesting that the products are more stable than the reactants. In the context of acid strength, a significant release of energy when NH4+ donates a proton may imply that it is a weak acid, as strong acids typically have more favorable dissociation energetics.
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Related Practice
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At 20 °C (approximately room temperature) the average velocity of N2 molecules in air is 1050 mph. (b) What is the kinetic energy (in J) of an N2 molecule moving at this speed?

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Textbook Question

Suppose an Olympic diver who weighs 52.0 kg executes a straight dive from a 10-m platform. At the apex of the dive, the diver is 10.8 m above the surface of the water. (a) What is the potential energy of the diver at the apex of the dive, relative to the surface of the water?

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Textbook Question

Suppose an Olympic diver who weighs 52.0 kg executes a straight dive from a 10-m platform. At the apex of the dive, the diver is 10.8 m above the surface of the water. (b) Assuming that all the potential energy of the diver is converted into kinetic energy at the surface of the water, at what speed, in m>s, will the diver enter the water?

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Textbook Question

Consider two solutions, the first being 50.0 mL of 1.00 M CuSO4 and the second 50.0 mL of 2.00 M KOH. When the two solutions are mixed in a constant-pressure calorimeter, a precipitate forms and the temperature of the mixture rises from 21.5 to 27.7 °C. (a) Before mixing, how many grams of Cu are present in the solution of CuSO4?

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Textbook Question
A sample of a hydrocarbon is combusted completely in O21g2 to produce 21.83 g CO21g2, 4.47 g H2O1g2, and 311 kJ of heat. (a) What is the mass of the hydrocarbon sample that was combusted?
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Textbook Question
The methane molecule, CH4, has the geometry shown in Figure 2.17. Imagine a hypothetical process in which the methane molecule is 'expanded,' by simultaneously extending all four C—H bonds to infinity. We then have the process CH41g2¡C1g2 + 4 H1g2 (a) Compare this process with the reverse of the reaction that represents the standard enthalpy of formation of CH41g2.
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