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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 37

Cobalt-60 is a strong gamma emitter that has a half-life of 5.26 yr. The cobalt-60 in a radiotherapy unit must be replaced when its radioactivity falls to 75% of the original sample. If an original sample was purchased in June 2016, when will it be necessary to replace the cobalt-60?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Half-Life

Half-life is the time required for half of the radioactive nuclei in a sample to decay. For Cobalt-60, which has a half-life of 5.26 years, this means that after this period, only 50% of the original amount remains. Understanding half-life is crucial for calculating how long it takes for a radioactive substance to reach a certain level of activity.
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Zero-Order Half-life

Radioactive Decay

Radioactive decay is the process by which an unstable atomic nucleus loses energy by emitting radiation. This decay occurs at a predictable rate, characterized by the half-life, and results in the transformation of the original isotope into a different element or isotope. In the context of Cobalt-60, it is important to know how much of the substance remains over time to assess its usability in applications like radiotherapy.
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Exponential Decay

Exponential decay describes the process where the quantity of a substance decreases at a rate proportional to its current value. In radioactive decay, this means that the amount of Cobalt-60 decreases exponentially over time, allowing us to calculate the remaining quantity after a certain number of half-lives. This concept is essential for determining when the radioactivity of Cobalt-60 falls to 75% of its original level.
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Related Practice
Textbook Question
Each statement that follows refers to a comparison between two radioisotopes, A and X. Indicate whether each of the following statements is true or false. (a) If the half-life for A is shorter than the half-life for X, A has a larger decay rate constant.
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Textbook Question

Some watch dials are coated with a phosphor, like ZnS, and a polymer in which some of the 1H atoms have been replaced by 3H atoms, tritium. The phosphor emits light when struck by the beta particle from the tritium decay, causing the dials to glow in the dark. The half-life of tritium is 12.3 yr. If the light given off is assumed to be directly proportional to the amount of tritium, by how much will a dial be dimmed in a watch that is 50 yr old?

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Textbook Question

It takes 4 h 39 min for a 2.00-mg sample of radium-230 to decay to 0.25 mg. What is the half-life of radium-230?

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Textbook Question

The cloth shroud from around a mummy is found to have a 14C activity of 9.7 disintegrations per minute per gram of carbon as compared with living organisms that undergo 16.3 disintegrations per minute per gram of carbon. From the half-life for 14C decay, 5715 yr, calculate the age of the shroud.

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Textbook Question

Potassium-40 decays to argon-40 with a half-life of 1.27 * 109 yr. What is the age of a rock in which the mass ratio of 40Ar to 40K is 4.2?

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Textbook Question

The thermite reaction, Fe2O31s2 + 2 Al1s2 ¡2 Fe1s2 + Al2O31s2, H = -851.5 kJ>mol, is one of the most exothermic reactions known. Because the heat released is sufficient to melt the iron product, the reaction is used to weld metal under the ocean. How much heat is released per mole of Al2O3 produced? How does this amount of thermal energy compare with the energy released when 2 mol of protons and 2 mol of neutrons combine to form 1 mol of alpha particles?

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