Skip to main content
Ch.21 - Nuclear Chemistry
Chapter 21, Problem 46

The thermite reaction, Fe2O31s2 + 2 Al1s2 ¡2 Fe1s2 + Al2O31s2, H = -851.5 kJ>mol, is one of the most exothermic reactions known. Because the heat released is sufficient to melt the iron product, the reaction is used to weld metal under the ocean. How much heat is released per mole of Al2O3 produced? How does this amount of thermal energy compare with the energy released when 2 mol of protons and 2 mol of neutrons combine to form 1 mol of alpha particles?

Verified step by step guidance
1
Identify the given enthalpy change (ΔH) for the reaction, which is -851.5 kJ. This value represents the heat released when the reaction proceeds as written.
Note that the stoichiometry of the reaction shows that 1 mole of Al2O3 is produced per reaction cycle. Therefore, the heat released per mole of Al2O3 produced is directly given by the ΔH of the reaction.
Understand that the comparison with nuclear reactions, such as the combination of protons and neutrons to form alpha particles, involves different scales of energy. Nuclear reactions typically release much greater amounts of energy per mole than chemical reactions.
To compare the energies, you would need the specific ΔH value for the nuclear reaction mentioned. This typically involves looking up or calculating the energy released based on mass defects and conversion into energy using Einstein's equation E=mc^2.
Finally, compare the magnitude of the energy released in the thermite reaction to that of the nuclear reaction to understand the scale and applications of each type of reaction.

Verified Solution

Video duration:
5m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Thermodynamics and Enthalpy

Thermodynamics is the study of energy transformations, and enthalpy (ΔH) is a key concept that measures the heat content of a system at constant pressure. In the thermite reaction, the negative ΔH value indicates that the reaction is exothermic, meaning it releases heat. Understanding how to interpret ΔH allows us to calculate the heat released per mole of products formed, such as Al2O3.
Recommended video:
Guided course
02:34
Enthalpy of Formation

Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions based on balanced equations. In the thermite reaction, the coefficients indicate the molar ratios of reactants and products. By applying stoichiometric principles, we can determine the amount of heat released per mole of Al2O3 produced by relating it to the total heat released in the reaction.
Recommended video:
Guided course
01:16
Stoichiometry Concept

Nuclear Reactions and Energy Release

Nuclear reactions, such as the fusion of protons and neutrons to form alpha particles, release energy due to the conversion of mass into energy, as described by Einstein's equation E=mc². This energy release is typically much greater than that of chemical reactions. Comparing the energy released in the thermite reaction with that from nuclear fusion highlights the significant differences in energy scales between chemical and nuclear processes.
Recommended video:
Guided course
02:06
Nuclear Binding Energy