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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 55c

Iodine-131 is a convenient radioisotope to monitor thyroid activity in humans. It is a beta emitter with a half-life of 8.02 days. The thyroid is the only gland in the body that uses iodine. A person undergoing a test of thyroid activity drinks a solution of NaI, in which only a small fraction of the iodide is radioactive. (c) A normal thyroid will take up about 12% of the ingested iodide in a few hours. How long will it take for the radioactive iodide taken up and held by the thyroid to decay to 0.01% of the original amount?

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1
Identify the initial and final percentages of the radioactive iodide. The initial uptake by the thyroid is 12% of the ingested iodide, and we want to find out when it decays to 0.01% of this initial amount.
Use the formula for radioactive decay: \( N = N_0 \times (0.5)^{t/t_{1/2}} \), where \( N \) is the final amount, \( N_0 \) is the initial amount, \( t \) is the time, and \( t_{1/2} \) is the half-life.
Substitute the known values into the decay formula. Here, \( N/N_0 = 0.01/12 \), and \( t_{1/2} = 8.02 \) days.
Solve the equation \( 0.01/12 = (0.5)^{t/8.02} \) for \( t \). This involves taking the logarithm of both sides to isolate \( t \).
Calculate \( t \) using the logarithmic form: \( t = t_{1/2} \times \frac{\log(0.01/12)}{\log(0.5)} \).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Radioactive Decay

Radioactive decay is the process by which an unstable atomic nucleus loses energy by emitting radiation. This decay occurs at a predictable rate characterized by the half-life, which is the time required for half of the radioactive substance to decay. Understanding this concept is crucial for calculating how long it will take for a given amount of a radioactive isotope, like iodine-131, to reduce to a specific fraction of its original quantity.
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Rate of Radioactive Decay

Half-Life

Half-life is a fundamental concept in nuclear chemistry that describes the time it takes for half of a sample of a radioactive substance to decay. For iodine-131, the half-life is 8.02 days, meaning that after this period, only half of the original amount remains. This concept is essential for determining the time required for the radioactive iodide in the thyroid to decay to a specified percentage of its initial amount.
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Exponential Decay

Exponential decay refers to the decrease of a quantity at a rate proportional to its current value, commonly observed in radioactive substances. The amount of radioactive material remaining can be modeled using the equation N(t) = N0 * (1/2)^(t/T), where N0 is the initial amount, T is the half-life, and t is the elapsed time. This mathematical relationship is vital for calculating how long it will take for the radioactive iodide in the thyroid to decay to 0.01% of its original amount.
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Related Practice
Open Question
The energy from solar radiation falling on Earth is 1.07 * 10^16 kJ/min. (a) How much loss of mass from the Sun occurs in one day from just the energy falling on Earth? (b) If the energy released in the reaction 235U + 10n → 14156Ba + 9236Kr + 310n (235U nuclear mass, 234.9935 amu; 141Ba nuclear mass, 140.8833 amu; 92Kr nuclear mass, 91.9021 amu) is taken as typical of that occurring in a nuclear reactor, what mass of uranium-235 is required to equal 0.10% of the solar energy that falls on Earth in 1.0 day?
Textbook Question

Based on the following atomic mass values: 1H, 1.00782 amu; 2H, 2.01410 amu; 3H, 3.01605 amu; 3He, 3.01603 amu; 4He, 4.00260 amu—and the mass of the neutron given in the text, calculate the energy released per mole in each of the following nuclear reactions, all of which are possibilities for a controlled fusion process:

(a) 21H + 31H → 42He + 10n

(b) 21H + 21H → 32He + 10n

(c) 21H + 32He → 42He + 11H

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Open Question
The isotope 6228Ni has the largest binding energy per nucleon of any isotope. Calculate this value from the atomic mass of nickel-62 (61.928345 amu) and compare it with the value given for iron-56 in Table 21.7.
Textbook Question

Why is it important that radioisotopes used as diagnostic tools in nuclear medicine produce gamma radiation when they decay? Why are alpha emitters not used as diagnostic tools?

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Open Question
(a) Which of the following are required characteristics of an isotope to be used as a fuel in a nuclear power reactor? (i) It must emit gamma radiation. (ii) On decay, it must release two or more neutrons. (iii) It must have a half-life of less than one hour. (iv) It must undergo fission upon the absorption of a neutron. (b) What is the most common fissionable isotope in a commercial nuclear power reactor?
Open Question
Which of the following statements about the uranium used in nuclear reactors is or are true? (i) Natural uranium has too little 235U to be used as a fuel. (ii) 238U cannot be used as a fuel because it forms a supercritical mass too easily. (iii) To be used as fuel, uranium must be enriched so that it is more than 50% 235U in composition. (iv) The neutron-induced fission of 235U releases more neutrons per nucleus than the fission of 238U.