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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 57

(a) Which of the following are required characteristics of an isotope to be used as a fuel in a nuclear power reactor? (i) It must emit gamma radiation. (ii) On decay, it must release two or more neutrons. (iii) It must have a half-life of less than one hour. (iv) It must undergo fission upon the absorption of a neutron. (b) What is the most common fissionable isotope in a commercial nuclear power reactor?

Verified step by step guidance
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Step 1: Understand the role of isotopes in nuclear reactors. Isotopes used as fuel in nuclear reactors must be capable of sustaining a chain reaction. This typically involves the isotope undergoing fission when it absorbs a neutron, releasing energy and additional neutrons.
Step 2: Evaluate each characteristic for part (a): (i) Emitting gamma radiation is not a requirement for an isotope to be used as fuel. (ii) Releasing two or more neutrons upon decay is important for sustaining a chain reaction, as these neutrons can induce fission in other nuclei. (iii) A half-life of less than one hour is impractical for reactor fuel, as it would decay too quickly. (iv) Undergoing fission upon neutron absorption is crucial for the isotope to be used as fuel.
Step 3: Identify the most common fissionable isotope for part (b). In commercial nuclear power reactors, the most common fissionable isotope is Uranium-235 (\(^{235}\text{U}\)). It is capable of sustaining a chain reaction and is used in most nuclear reactors.
Step 4: Consider the properties of Uranium-235. \(^{235}\text{U}\) undergoes fission when it absorbs a neutron, releasing energy and additional neutrons, which can then induce fission in other \(^{235}\text{U}\) nuclei, sustaining the chain reaction.
Step 5: Summarize the key characteristics of a suitable isotope for nuclear fuel: It should undergo fission upon neutron absorption and release multiple neutrons to sustain a chain reaction. The most common isotope used is \(^{235}\text{U}\).
Related Practice
Open Question
The isotope 6228Ni has the largest binding energy per nucleon of any isotope. Calculate this value from the atomic mass of nickel-62 (61.928345 amu) and compare it with the value given for iron-56 in Table 21.7.
Textbook Question

Iodine-131 is a convenient radioisotope to monitor thyroid activity in humans. It is a beta emitter with a half-life of 8.02 days. The thyroid is the only gland in the body that uses iodine. A person undergoing a test of thyroid activity drinks a solution of NaI, in which only a small fraction of the iodide is radioactive. (c) A normal thyroid will take up about 12% of the ingested iodide in a few hours. How long will it take for the radioactive iodide taken up and held by the thyroid to decay to 0.01% of the original amount?

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Textbook Question

Why is it important that radioisotopes used as diagnostic tools in nuclear medicine produce gamma radiation when they decay? Why are alpha emitters not used as diagnostic tools?

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Open Question
Which of the following statements about the uranium used in nuclear reactors is or are true? (i) Natural uranium has too little 235U to be used as a fuel. (ii) 238U cannot be used as a fuel because it forms a supercritical mass too easily. (iii) To be used as fuel, uranium must be enriched so that it is more than 50% 235U in composition. (iv) The neutron-induced fission of 235U releases more neutrons per nucleus than the fission of 238U.
Open Question
What is the function of the control rods in a nuclear reactor? What substances are used to construct the control rods? Why are these substances chosen?
Textbook Question

(c) What other substances are used as a moderator in nuclear reactor designs?

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