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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 60c

(c) What other substances are used as a moderator in nuclear reactor designs?

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1. A moderator in a nuclear reactor is a substance that slows down the neutrons produced during the fission process. The slowed down neutrons are more likely to cause further fission reactions, thus sustaining the chain reaction.
2. The most commonly used moderator is water, specifically light water or heavy water. Light water is ordinary water (H2O), while heavy water is water where the hydrogen atoms are replaced by deuterium (D2O).
3. Besides water, other substances can also be used as moderators. These include graphite (carbon) and beryllium. Graphite was used in the first nuclear reactors built by man, while beryllium is used in some advanced reactor designs.
4. The choice of moderator depends on various factors such as the type of reactor, the fuel used, and the desired neutron energy spectrum. Each moderator has its own advantages and disadvantages.
5. For example, water is cheap and readily available, but it also absorbs neutrons, reducing the efficiency of the reactor. Graphite does not absorb neutrons as much, but it can catch fire in case of a reactor accident. Beryllium is a good moderator and reflector of neutrons, but it is more expensive and less common than water or graphite.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Nuclear Moderators

Nuclear moderators are materials used in nuclear reactors to slow down fast neutrons produced during fission. By reducing the speed of these neutrons, moderators increase the likelihood of further fission reactions, enhancing the reactor's efficiency. Common moderators include water, heavy water, and graphite, each with distinct properties that affect reactor design and operation.
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Types of Moderators

Different types of moderators can be employed in nuclear reactors, each influencing the reactor's performance. Light water (ordinary water) is the most widely used, while heavy water (deuterium oxide) allows for a more efficient reaction with natural uranium. Graphite, another common moderator, is used in some reactor designs for its ability to absorb fewer neutrons, thus maintaining a higher neutron economy.
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Reactor Design Considerations

The choice of moderator is crucial in reactor design as it affects the reactor's criticality, safety, and fuel efficiency. Factors such as neutron absorption cross-section, heat capacity, and chemical stability under radiation are considered when selecting a moderator. The design must balance these factors to optimize performance while ensuring safety and regulatory compliance.
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Related Practice
Open Question
(a) Which of the following are required characteristics of an isotope to be used as a fuel in a nuclear power reactor? (i) It must emit gamma radiation. (ii) On decay, it must release two or more neutrons. (iii) It must have a half-life of less than one hour. (iv) It must undergo fission upon the absorption of a neutron. (b) What is the most common fissionable isotope in a commercial nuclear power reactor?
Open Question
Which of the following statements about the uranium used in nuclear reactors is or are true? (i) Natural uranium has too little 235U to be used as a fuel. (ii) 238U cannot be used as a fuel because it forms a supercritical mass too easily. (iii) To be used as fuel, uranium must be enriched so that it is more than 50% 235U in composition. (iv) The neutron-induced fission of 235U releases more neutrons per nucleus than the fission of 238U.
Open Question
What is the function of the control rods in a nuclear reactor? What substances are used to construct the control rods? Why are these substances chosen?
Textbook Question

Complete and balance the nuclear equations for the following fission or fusion reactions:

(a) 21H + 21H → 32He + _

(b) 23992U + 10n¡ → 13351Sb + 9841Nb + _ 10n

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Textbook Question

Complete and balance the nuclear equations for the following fission reactions:

(a) 23592U + 10n → 16062Sm + 7230Zn + _ 10n

(b) 23994Pu + 10n → 14458Ce + _ + 2 10n

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Open Question
A portion of the Sun’s energy comes from the reaction 4 11H → 42He + 2 0-1e, which requires a temperature of 106 to 107 K. Use the mass of the helium-4 nucleus given in Table 21.7 to determine how much energy is released per mol of hydrogen atoms.