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Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 34

Consider two solutions, solution A and solution B. The concentration of 3H+4 in solution A is 250 times greater than that in solution B. What is the difference in the pH values of the two solutions?

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Step 1: Understand the relationship between hydrogen ion concentration and pH. The pH of a solution is calculated using the formula: \( \text{pH} = -\log[\text{H}^+] \), where \([\text{H}^+]\) is the concentration of hydrogen ions in moles per liter.
Step 2: Let \([\text{H}^+]_B\) be the concentration of hydrogen ions in solution B. Then, the concentration of hydrogen ions in solution A, \([\text{H}^+]_A\), is 250 times \([\text{H}^+]_B\). Therefore, \([\text{H}^+]_A = 250 \times [\text{H}^+]_B\).
Step 3: Calculate the pH of solution A using the formula: \( \text{pH}_A = -\log([\text{H}^+]_A) = -\log(250 \times [\text{H}^+]_B) \).
Step 4: Calculate the pH of solution B using the formula: \( \text{pH}_B = -\log([\text{H}^+]_B) \).
Step 5: Determine the difference in pH between the two solutions by subtracting the pH of solution B from the pH of solution A: \( \Delta \text{pH} = \text{pH}_A - \text{pH}_B \).
Related Practice
Textbook Question
Which of the following solutions is the most basic? (a) 0.6 M NaCl, (b) 0.150 M CsOH, (c) 0.100 M Sr1OH22.
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Textbook Question

Deuterium oxide 1D2O, where D is deuterium, the hydrogen-2 isotope) has an ion-product constant, Kw, of 8.9 * 10-16 at 20 °C. Calculate 3D+4 and 3OD-4 for pure (neutral) D2O at this temperature.

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Textbook Question

By what factor does 3H+4 change for a pH change of (a) 2.00 units?

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Open Question
Complete the following table by calculating the missing entries and indicating whether the solution is acidic or basic.
Open Question
Complete the following table by calculating the missing entries. In each case, indicate whether the solution is acidic or basic.
Textbook Question

The average pH of normal arterial blood is 7.40. At normal body temperature 137 °C2, Kw = 2.4 * 10-14. Calculate 3H+4, 3OH-4, and pOH for blood at this temperature.

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