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Ch.16 - Acid-Base Equilibria
Chapter 16, Problem 33a

By what factor does 3H+4 change for a pH change of (a) 2.00 units?

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pH is a measure of the hydrogen ion concentration in a solution, given by the formula: \( \text{pH} = -\log[\text{H}^+] \).
A change in pH of 2.00 units means the pH has either increased or decreased by 2.00.
If the pH decreases by 2.00 units, the concentration of \( \text{H}^+ \) ions increases. Conversely, if the pH increases by 2.00 units, the concentration of \( \text{H}^+ \) ions decreases.
The relationship between pH change and \( \text{H}^+ \) concentration change is logarithmic. A change of 1 pH unit corresponds to a tenfold change in \( \text{H}^+ \) concentration.
Therefore, a change of 2.00 pH units corresponds to a change in \( \text{H}^+ \) concentration by a factor of \( 10^2 \).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

pH Scale

The pH scale measures the acidity or basicity of a solution, ranging from 0 to 14. A pH of 7 is neutral, below 7 is acidic, and above 7 is basic. Each unit change in pH represents a tenfold change in hydrogen ion concentration, meaning that a decrease in pH indicates an increase in acidity.
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Hydrogen Ion Concentration

Hydrogen ion concentration, denoted as [H+], is a measure of the amount of hydrogen ions present in a solution. It is directly related to pH, where a lower pH corresponds to a higher concentration of H+. For example, a change of 2.00 units in pH results in a change in [H+] by a factor of 10^2, or 100 times.
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Logarithmic Relationship

The relationship between pH and hydrogen ion concentration is logarithmic, meaning that pH is the negative logarithm of the hydrogen ion concentration: pH = -log[H+]. This implies that small changes in pH can lead to significant changes in [H+], which is crucial for understanding how acidity affects chemical reactions and biological processes.
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Related Practice
Textbook Question
Which of the following solutions is the most acidic? (a) 0.2 M Ba(OH)2, (b) 0.2 M H2SO3, (c) 1.0 M glucose 1C6H12O6).
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Textbook Question
Which of the following solutions is the most basic? (a) 0.6 M NaCl, (b) 0.150 M CsOH, (c) 0.100 M Sr1OH22.
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Textbook Question

Deuterium oxide 1D2O, where D is deuterium, the hydrogen-2 isotope) has an ion-product constant, Kw, of 8.9 * 10-16 at 20 °C. Calculate 3D+4 and 3OD-4 for pure (neutral) D2O at this temperature.

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Open Question
Consider two solutions, solution A and solution B. The concentration of 3H+4 in solution A is 250 times greater than that in solution B. What is the difference in the pH values of the two solutions?
Open Question
Complete the following table by calculating the missing entries and indicating whether the solution is acidic or basic.
Open Question
Complete the following table by calculating the missing entries. In each case, indicate whether the solution is acidic or basic.