Chapter 15, Problem 28
Consider the equilibrium N2(π) + O2(π) + Br2(π) β 2 NOBr(π) Calculate the equilibrium constant πΎπ for this reaction, given the following information at 298 K:
2 NO(π) + Br2(π) β 2 NOBr(π) πΎπ = 2.02
NO(π) β N2(π) + O2(π) πΎπ = 2.1Γ1030
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At 1000 K, πΎπ = 1.85 for the reaction SO2(π) + 12 O2(π) β SO3(π) (c) What is the value of πΎπ for the reaction in part (b)?
Consider the following equilibrium, for which πΎπ = 0.0752 at 480Β°C: 2 Cl2(π) + 2 H2O(π) β 4 HCl(π) + O2(π) (a) What is the value of πΎπ for the reaction 4 HCl(π) + O2(π) β 2 Cl2(π) + 2 H2O(π)?
The following equilibria were attained at 823 K:
CoO(s) + H2(g) β Co(s) + H2O(g) Kc = 67
CoO(s) + CO(g) β Co(s) + CO2(g) Kc = 490
Based on these equilibria, calculate the equilibrium constant for H2(g) + CO2(g) β CO(g) + H2O(g) at 823 K.
The equilibrium 2 NO(π) + Cl2(π) β 2 NOCl(π) is established at 500.0 K. An equilibrium mixture of the three gases has partial pressures of 0.095 atm, 0.171 atm, and 0.28 atm for NO, Cl2, and NOCl, respectively. (a) Calculate πΎπ for this reaction at 500.0 K.
The equilibrium 2 NO(π) + Cl2(π) β 2 NOCl(π) is established at 500.0 K. An equilibrium mixture of the three gases has partial pressures of 0.095 atm, 0.171 atm, and 0.28 atm for NO, Cl2, and NOCl, respectively. (b) If the vessel has a volume of 5.00 L, calculate Kc at this temperature.
Phosphorus trichloride gas and chlorine gas react to form phosphorus pentachloride gas: PCl3(π) + Cl2(π) β PCl5(π). A 7.5-L gas vessel is charged with a mixture of PCl3(π) and Cl2(π), which is allowed to equilibrate at 450 K. At equilibrium the partial pressures of the three gases are πPCl3 = 0.124 atm, πCl2 = 0.157 atm, and πPCl5 = 1.30 atm. (a) What is the value of πΎπ at this temperature?