Chapter 15, Problem 26a
Consider the following equilibrium, for which πΎπ = 0.0752 at 480Β°C: 2 Cl2(π) + 2 H2O(π) β 4 HCl(π) + O2(π) (a) What is the value of πΎπ for the reaction 4 HCl(π) + O2(π) β 2 Cl2(π) + 2 H2O(π)?
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If πΎπ = 0.042 for PCl3(π) + Cl2(π) β PCl5(π) at 500 K, what is the value of πΎπ for this reaction at this temperature?
Consider the following equilibrium: 2 H2(π) + S2(βπ) β 2 H2S(π) πΎπ = 1.08Γ107 at 700Β°C (c) Calculate the value of πΎπ if you rewrote the equation H2(π) + 1/2 S2(βπ) β H2S(π)
At 1000 K, πΎπ = 1.85 for the reaction SO2(π) + 12 O2(π) β SO3(π) (c) What is the value of πΎπ for the reaction in part (b)?
The following equilibria were attained at 823 K:
CoO(s) + H2(g) β Co(s) + H2O(g) Kc = 67
CoO(s) + CO(g) β Co(s) + CO2(g) Kc = 490
Based on these equilibria, calculate the equilibrium constant for H2(g) + CO2(g) β CO(g) + H2O(g) at 823 K.
Consider the equilibrium N2(π) + O2(π) + Br2(π) β 2 NOBr(π) Calculate the equilibrium constant πΎπ for this reaction, given the following information at 298 K:
2 NO(π) + Br2(π) β 2 NOBr(π) πΎπ = 2.02
NO(π) β N2(π) + O2(π) πΎπ = 2.1Γ1030
The equilibrium 2 NO(π) + Cl2(π) β 2 NOCl(π) is established at 500.0 K. An equilibrium mixture of the three gases has partial pressures of 0.095 atm, 0.171 atm, and 0.28 atm for NO, Cl2, and NOCl, respectively. (a) Calculate πΎπ for this reaction at 500.0 K.