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Ch.14 - Chemical Kinetics

Chapter 14, Problem 107d

The following mechanism has been proposed for the reaction of NO with H2 to form N2O and H2O: NO1g2 + NO1g2¡N2O21g2 N2O21g2 + H21g2¡N2O1g2 + H2O1g2 (d) The observed rate law is rate = k3NO423H24. If the proposed mechanism is correct, what can we conclude about the relative speeds of the first and second reactions?

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Hello everyone today. We are being told that there is a reaction between nitric oxide and carbon monoxide. That takes place in two steps. The first step involves two nitric oxide molecules coming together. And the second step involves one nitrous oxide and one carbon monoxide molecule coming together. And so the first thing I wanna do is you want to write the rate laws for each step. So for step one the rate law for this reaction would just simply be that the rate is equal to some constant K. That's times are multiplied by nitric oxide, N. 02. And since there's two of them coming together, we square it for our second step. So step to the first step one the rate would be equal to K. Or some constant times a three molecule times a carbon monoxide molecule. And so the rate law. The second step involves this N. 03 and this C. O molecule. And if it were the rate determining step, then C. O. Or carbon monoxide would be the term in the actual rate law which we saw from the question stem that the rate is equal to K. Times nitric oxide squared. And so since there actually is no C. O. Or carbon monoxide in the rate law, the first step step, one must be the rate law. So the first step must be the slow step. While the second step must be the fast step overall, I hope this helped. And until next time
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Textbook Question

The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (c) Calculate the half-life of the reaction.

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Textbook Question

The rate of a first-order reaction is followed by spectroscopy, monitoring the absorbance of a colored reactant at 520 nm. The reaction occurs in a 1.00-cm sample cell, and the only colored species in the reaction has an extinction coefficient of 5.60 * 103 M-1 cm-1 at 520 nm. (d) How long does it take for the absorbance to fall to 0.100?

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At 28 C, raw milk sours in 4.0 h but takes 48 h to sour in a refrigerator at 5 C. Estimate the activation energy in kJ>mol for the reaction that leads to the souring of milk.

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Textbook Question

Ozone in the upper atmosphere can be destroyed by the following two-step mechanism: Cl1g2 + O31g2¡ClO1g2 + O21g2 ClO1g2 + O1g2¡Cl1g2 + O21g2 (b) What is the catalyst in the reaction?

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Textbook Question

The gas-phase decomposition of ozone is thought to occur by the following two-step mechanism.

Step 1: O3(g) ⇌ O2(g) + O(g) (fast)

Step 2: O(g) + O3(g) → 2 O2 (slow)

(b) Derive the rate law that is consistent with this mechanism. (Hint: The product appears in the rate law.)

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Textbook Question

The gas-phase decomposition of ozone is thought to occur by the following two-step mechanism.

Step 1: O3(g) ⇌ O2(g) + O(g) (fast)

Step 2: O(g) + O3(g) → 2 O2 (slow)

(d) If instead the reaction occurred in a single step, would the rate law change? If so, what would it be?

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