Chapter 14, Problem 53
Calculate the fraction of atoms in a sample of argon gas at 400 K that has an energy of 10.0 kJ or greater.
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Sucrose 1C12H22O112, commonly known as table sugar, reacts in dilute acid solutions to form two simpler sugars, glucose and fructose, both of which have the formula C6H12O6. At 23 C and in 0.5 M HCl, the following data were obtained for the disappearance of sucrose: Time (min) 3C12H22o11 4 1M2 0 0.316 39 0.274 80 0.238 140 0.190 210 0.146 (a) Is the reaction first order or second order with respect to 3C12H22O114?
(a) What factors determine whether a collision between two molecules will lead to a chemical reaction?
(b) Does the rate constant for a reaction generally increase or decrease with an increase in reaction temperature?
(a) The activation energy for the isomerization of methyl isonitrile (Figure 14.6) is 160 kJ>mol. Calculate the fraction of methyl isonitrile molecules that has an energy equal to or greater than the activation energy at 500 K. (b) Calculate this fraction for a temperature of 520 K. What is the ratio of the fraction at 520 K to that at 500 K?
The gas-phase reaction Cl(g) + HBr(g) → HCl(g) + Br(g) has an overall energy change of -66 kJ. The activation energy for the reaction is 7 kJ. (a) Sketch the energy profile for the reaction, and label Ea and ΔE.
The gas-phase reaction Cl(g) + HBr(g) → HCl(g) + Br(g) has an overall energy change of -66 kJ. The activation energy for the reaction is 7 kJ. (b) What is the activation energy for the reverse reaction?