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Ch.14 - Chemical Kinetics
Chapter 14, Problem 51a

(a) What factors determine whether a collision between two molecules will lead to a chemical reaction?

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Identify the kinetic energy of the colliding molecules. The molecules must have sufficient kinetic energy to overcome the activation energy barrier of the reaction.
Consider the orientation of the molecules during collision. The molecules must be oriented in a specific way that allows for the proper alignment of atoms that will bond together.
Examine the molecular structure and the presence of any functional groups that might influence the reaction pathway or the stability of the transition state.
Assess the reaction conditions such as temperature and pressure, as these can affect the kinetic energy of the molecules and the frequency of collisions.
Evaluate the presence of catalysts, which can lower the activation energy and change the required orientation for a successful reaction.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Collision Theory

Collision theory posits that for a chemical reaction to occur, reactant molecules must collide with sufficient energy and proper orientation. The energy of the collision must be equal to or greater than the activation energy, which is the minimum energy required to initiate a reaction. Additionally, the orientation of the colliding molecules must allow for the formation of new bonds.
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Activation Energy

Activation energy is the energy barrier that must be overcome for a reaction to proceed. It represents the minimum energy required for reactants to transform into products. Factors such as temperature and the presence of catalysts can influence the activation energy, thereby affecting the rate of the reaction by increasing the number of effective collisions.
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Molecular Orientation

Molecular orientation refers to the specific alignment of molecules during a collision. For a reaction to occur, the molecules must collide in a way that allows for the breaking and forming of bonds. This means that certain orientations are more favorable than others, and understanding these orientations can help predict the likelihood of a reaction occurring during molecular collisions.
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