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Ch.14 - Chemical Kinetics
Chapter 14, Problem 51a

(a) What factors determine whether a collision between two molecules will lead to a chemical reaction?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Collision Theory

Collision theory posits that for a chemical reaction to occur, reactant molecules must collide with sufficient energy and proper orientation. The energy of the collision must be equal to or greater than the activation energy, which is the minimum energy required to initiate a reaction. Additionally, the orientation of the colliding molecules must allow for the formation of new bonds.
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Activation Energy

Activation energy is the energy barrier that must be overcome for a reaction to proceed. It represents the minimum energy required for reactants to transform into products. Factors such as temperature and the presence of catalysts can influence the activation energy, thereby affecting the rate of the reaction by increasing the number of effective collisions.
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Molecular Orientation

Molecular orientation refers to the specific alignment of molecules during a collision. For a reaction to occur, the molecules must collide in a way that allows for the breaking and forming of bonds. This means that certain orientations are more favorable than others, and understanding these orientations can help predict the likelihood of a reaction occurring during molecular collisions.
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Related Practice
Textbook Question

Consider the data presented in Exercise 14.19. (c) What is the half-life for the reaction?

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Textbook Question

The gas-phase decomposition of NO2, 2 NO21g2¡ 2 NO1g2 + O21g2, is studied at 383 C, giving the following data: Time (s) 3no2 4 (M) 0.0 0.100 5.0 0.017 10.0 0.0090 15.0 0.0062 20.0 0.0047 (c) Predict the reaction rates at the beginning of the reaction for initial concentrations of 0.200 M, 0.100 M, and 0.050 M NO2.

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Textbook Question

Sucrose 1C12H22O112, commonly known as table sugar, reacts in dilute acid solutions to form two simpler sugars, glucose and fructose, both of which have the formula C6H12O6. At 23 C and in 0.5 M HCl, the following data were obtained for the disappearance of sucrose: Time (min) 3C12H22o11 4 1M2 0 0.316 39 0.274 80 0.238 140 0.190 210 0.146 (a) Is the reaction first order or second order with respect to 3C12H22O114?

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Textbook Question

(b) Does the rate constant for a reaction generally increase or decrease with an increase in reaction temperature?

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Textbook Question

Calculate the fraction of atoms in a sample of argon gas at 400 K that has an energy of 10.0 kJ or greater.

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Textbook Question

(a) The activation energy for the isomerization of methyl isonitrile (Figure 14.6) is 160 kJ>mol. Calculate the fraction of methyl isonitrile molecules that has an energy equal to or greater than the activation energy at 500 K. (b) Calculate this fraction for a temperature of 520 K. What is the ratio of the fraction at 520 K to that at 500 K?

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