Chapter 14, Problem 55b
The gas-phase reaction Cl(g) + HBr(g) → HCl(g) + Br(g) has an overall energy change of -66 kJ. The activation energy for the reaction is 7 kJ. (b) What is the activation energy for the reverse reaction?
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Calculate the fraction of atoms in a sample of argon gas at 400 K that has an energy of 10.0 kJ or greater.
(a) The activation energy for the isomerization of methyl isonitrile (Figure 14.6) is 160 kJ>mol. Calculate the fraction of methyl isonitrile molecules that has an energy equal to or greater than the activation energy at 500 K. (b) Calculate this fraction for a temperature of 520 K. What is the ratio of the fraction at 520 K to that at 500 K?
The gas-phase reaction Cl(g) + HBr(g) → HCl(g) + Br(g) has an overall energy change of -66 kJ. The activation energy for the reaction is 7 kJ. (a) Sketch the energy profile for the reaction, and label Ea and ΔE.
Indicate whether each statement is true or false. (c) Increasing the reaction temperature increases the fraction of successful collisions between reactants.
Indicate whether each statement is true or false. (a) If you measure the rate constant for a reaction at different temperatures, you can calculate the overall enthalpy change for the reaction.
Indicate whether each statement is true or false. (b) Exothermic reactions are faster than endothermic reactions.