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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 53a

Which would you expect to be the more ductile element, (a) Ag or Mo? In each case explain your reasoning.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ductility

Ductility is a measure of a material's ability to deform under tensile stress, which is often characterized by the material's ability to be stretched into a wire. Metals typically exhibit high ductility due to the presence of metallic bonds that allow atoms to slide past one another without breaking the overall structure. This property is crucial in applications where materials need to be shaped or drawn into wires.

Metallic Bonding

Metallic bonding is a type of chemical bonding that occurs between metal atoms, characterized by a 'sea of electrons' that are free to move around. This delocalization of electrons allows metals to conduct electricity and heat efficiently, as well as contributing to their malleability and ductility. The strength and nature of these bonds can vary between different metals, influencing their physical properties.
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Comparison of Silver (Ag) and Molybdenum (Mo)

Silver (Ag) is known for its high ductility and malleability, making it one of the most ductile metals. In contrast, Molybdenum (Mo) is a transition metal that, while strong and resistant to heat, is less ductile than silver. The differences in their atomic structure and bonding lead to silver being more easily drawn into wires compared to molybdenum, which is more brittle.
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Related Practice
Textbook Question

The molecular-orbital diagrams for two- and four-atom linear chains of lithium atoms are shown in Figure 12.22. Construct a molecular-orbital diagram for a chain containing six lithium atoms and use it to answer the following questions: (c) How many nodes are in the highest-energy molecular orbital?

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Textbook Question

The molecular-orbital diagrams for two- and four-atom linear chains of lithium atoms are shown in Figure 12.22. Construct a molecular-orbital diagram for a chain containing six lithium atoms and use it to answer the following questions: (e) How many nodes are in the lowest-energy unoccupied molecular orbital (LUMO)?

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Textbook Question

Repeat Exercise 12.51 for a linear chain of eight lithium atoms. (f) How does the HOMO–LUMO energy gap for this case compare to that of the four-atom case?

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Textbook Question

Which of the following statements does not follow from the fact that the alkali metals have relatively weak metal–metal bonding? (a) The alkali metals are less dense than other metals. (b) The alkali metals are soft enough to be cut with a knife. (c) The alkali metals are more reactive than other metals. (d) The alkali metals have higher melting points than other metals. (e) The alkali metals have low ionization energies.

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Textbook Question
For each of the following groups, which metal would you expect to have the highest melting point: (b) rubidium, molybdenum, or indium?
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Textbook Question

Tausonite, a mineral composed of Sr, O, and Ti, has the cubic unit cell shown in the drawing. (a) What is the empirical formula of this mineral?

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