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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 12a

Silicon is the fundamental component of integrated circuits. Si has the same structure as diamond. (a) Is Si a molecular, metallic, ionic, or covalent-network solid?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Types of Solids

Solids can be classified into four main types: molecular, metallic, ionic, and covalent-network solids. Molecular solids consist of molecules held together by intermolecular forces, metallic solids are composed of metal atoms sharing electrons, ionic solids are formed from the electrostatic attraction between ions, and covalent-network solids consist of a continuous network of covalent bonds, leading to high melting points and hardness.
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Covalent-Network Solids

Covalent-network solids are characterized by a three-dimensional network of covalent bonds, which results in strong interatomic interactions. This structure gives these materials high melting points and significant hardness. Diamond is a classic example, and silicon (Si) shares a similar tetrahedral bonding arrangement, making it a covalent-network solid.
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Silicon in Electronics

Silicon is a crucial element in the electronics industry, primarily due to its semiconducting properties. Its ability to form a covalent-network solid allows for the manipulation of its electrical conductivity through doping, which is essential for creating integrated circuits. Understanding silicon's structure helps explain its role in technology and materials science.
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