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Ch.11 - Liquids and Intermolecular Forces
Chapter 11, Problem 40d

Name the phase transition in each of the following situations and indicate whether it is exothermic or endothermic: (d) Molten lava from a volcano turns into solid rock.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Phase Transition

A phase transition refers to the transformation of a substance from one state of matter to another, such as solid, liquid, or gas. Common examples include melting (solid to liquid) and freezing (liquid to solid). Understanding these transitions is crucial for analyzing changes in physical properties and energy exchanges during the process.
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Exothermic and Endothermic Processes

Exothermic processes release energy, usually in the form of heat, to the surroundings, while endothermic processes absorb energy from the surroundings. The classification of a phase transition as exothermic or endothermic depends on whether energy is released or absorbed during the transition. For instance, freezing is exothermic as it releases heat.
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Freezing of Lava

When molten lava cools and solidifies into rock, it undergoes a phase transition known as freezing. This process is exothermic because the lava releases heat to the environment as it transitions from a liquid state to a solid state. Understanding this transition helps in grasping the geological processes involved in volcanic activity.
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Related Practice
Textbook Question

Liquids can interact with flat surfaces just as they can with capillary tubes; the cohesive forces within the liquid can be stronger or weaker than the adhesive forces between liquid and surface:

(b) Which of these diagrams, i or ii, rep- resents what happens when water is on a nonpolar surface?

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Textbook Question
The boiling points, surface tensions, and viscosities of water and several alcohols are as shown below: (b) How do you explain the fact that propanol and ethylene glycol have similar molecular weights (60 versus 62 amu), yet the viscosity of ethylene glycol is more than 10 times larger than propa- nol?
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Textbook Question

Name the phase transition in each of the following situations and indicate whether it is exothermic or endothermic: (c) Rubbing alcohol in an open container slowly disappears.

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Textbook Question

Ethyl chloride (C2H5Cl) boils at 12 °C. When liquid C2H5Cl under pressure is sprayed on a room-temperature (25 °C) surface in air, the surface is cooled considerably. (a) What does this observation tell us about the specific heat of C2H5Cl(g) as compared with that of C2H5Cl(l)?

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Textbook Question

Ethyl chloride (C2H5Cl) boils at 12 °C. When liquid C2H5Cl under pressure is sprayed on a room-temperature (25 °C) surface in air, the surface is cooled considerably. (b) Assume that the heat lost by the surface is gained by ethyl chloride. What enthalpies must you consider if you were to calculate the final temperature of the surface?

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Textbook Question

For many years drinking water has been cooled in hot climates by evaporating it from the surfaces of canvas bags or porous clay pots. How many grams of water can be cooled from 35 to 20 °C by the evaporation of 60 g of water? (The heat of vaporization of water in this temperature range is 2.4 kJ/g. The specific heat of water is 4.18 J/g-K).

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