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Ch.11 - Liquids and Intermolecular Forces
Chapter 11, Problem 43

For many years drinking water has been cooled in hot climates by evaporating it from the surfaces of canvas bags or porous clay pots. How many grams of water can be cooled from 35 to 20 °C by the evaporation of 60 g of water? (The heat of vaporization of water in this temperature range is 2.4 kJ/g. The specific heat of water is 4.18 J/g-K).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Heat of Vaporization

The heat of vaporization is the amount of energy required to convert a unit mass of a liquid into vapor without a change in temperature. For water, this value is significant because it indicates how much heat energy is absorbed during the evaporation process. In this question, the heat of vaporization is given as 2.4 kJ/g, which will be crucial for calculating how much water can be cooled by the evaporation of 60 g of water.
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Heat Capacity

Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius (or Kelvin). For water, the specific heat capacity is 4.18 J/g-K, meaning it takes 4.18 joules to raise the temperature of 1 gram of water by 1 °C. This concept is essential for determining how much heat energy is needed to cool the water from 35 °C to 20 °C in the problem.
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Heat Capacity

Energy Conservation in Phase Changes

Energy conservation in phase changes refers to the principle that energy is neither created nor destroyed but can change forms. In this context, the energy lost by the water being cooled must equal the energy gained by the evaporating water. This relationship allows us to set up an equation to find out how much water can be cooled by the evaporation of a specific mass of water, linking the heat of vaporization and the specific heat capacity.
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Entropy in Phase Changes
Related Practice
Textbook Question

Name the phase transition in each of the following situations and indicate whether it is exothermic or endothermic: (d) Molten lava from a volcano turns into solid rock.

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Textbook Question

Ethyl chloride (C2H5Cl) boils at 12 °C. When liquid C2H5Cl under pressure is sprayed on a room-temperature (25 °C) surface in air, the surface is cooled considerably. (a) What does this observation tell us about the specific heat of C2H5Cl(g) as compared with that of C2H5Cl(l)?

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Textbook Question

Ethyl chloride (C2H5Cl) boils at 12 °C. When liquid C2H5Cl under pressure is sprayed on a room-temperature (25 °C) surface in air, the surface is cooled considerably. (b) Assume that the heat lost by the surface is gained by ethyl chloride. What enthalpies must you consider if you were to calculate the final temperature of the surface?

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Textbook Question

The critical temperatures and pressures of a series of halogenated methanes are as follows:

(a) List the intermolecular forces that occur for each compound.

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Textbook Question

The critical temperatures and pressures of a series of halogenated methanes are as follows: (c) Predict the critical temperature and pressure for CCl4 based on the trends in this table. Look up the experimentally determined critical temperatures and pressures for CCl4, using a source such as the CRC Handbook of Chemistry and Physics, and suggest a reason for any discrepancies.

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Textbook Question

(a) Place the following substances in order of increasing volatility: CH4, CBr4, CH2Cl2, CH3Cl, CHBr3, and CH2Br2. (b) How do the boiling points vary through this series? (c) Explain your answer to part (b) in terms of intermolecular forces.

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