Chapter 4, Problem 152
Assume that you dissolve 10.0 g of a mixture of NaOH and Ba(OH)2 in 250.0 mL of water and titrate with 1.50 M hydrochloric acid. The titration is complete after 108.9 mL of the acid has been added. What is the mass in grams of each substance in the mixture?
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A 1.268 g sample of a metal carbonate (MCO3) was treated with 100.00 mL of 0.1083 M sulfuric acid (H2SO4), yielding CO2 gas and an aqueous solution of the metal sulfate (MSO4). The solution was boiled to remove all the dissolved CO2 and was then titrated with 0.1241 M NaOH. A 71.02 mL volume of NaOH was required to neutralize the excess H2SO4. (a) What is the identity of the metal M?
(b) How many liters of CO2 gas were produced if the density of CO2 is 1.799 g/L?
Element M is prepared industrially by a two-step procedure according to the following (unbalanced) equations:
Assume that 0.855 g of M2O3 is submitted to the reaction sequence. When the HCl produced in step (2) is dissolved in water and titrated with 0.511 M NaOH, 144.2 mL of the NaOH solution is required to neutralize the HCl. (a) Balance both equations.
To 100.0 mL of a solution that contains 0.120 M Cr(NO3)2 and 0.500 M HNO3 is added to 20.0 mL of 0.250 M K2Cr2O7. The dichromate and chromium(II) ions react to give chromium(III) ions. (a) Write a balanced net ionic equation for the reaction.
(b) Calculate the concentrations of all ions in the solution after reaction. Check your concentrations to make sure that the solution is electrically neutral.