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Ch 19: The First Law of Thermodynamics
Chapter 19, Problem 19

Two moles of an ideal gas are heated at constant pressure from T = 27°C to T = 107°C. (a) Draw a pV-diagram for this process. (ANSWER IS )

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1
Convert the initial and final temperatures from Celsius to Kelvin by adding 273.15 to each. This is because the ideal gas law and related calculations require temperature in Kelvin.
Identify that the process is at constant pressure, which means the pressure (p) does not change. On a pV-diagram, this is represented by a horizontal line.
Use the ideal gas law, PV = nRT, to understand how the volume (V) changes with temperature (T) when the number of moles (n) and the gas constant (R) are constant. Since the pressure is constant and the temperature increases, the volume must also increase.
Calculate the initial and final volumes using the ideal gas law. Since the pressure is constant, the ratio of volumes is equal to the ratio of temperatures (V2/V1 = T2/T1).
Sketch the pV-diagram: Start by plotting the initial state at the calculated initial volume and constant pressure. Then draw a line horizontally to the right to the calculated final volume at the same pressure level, indicating an increase in volume.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of an ideal gas through the equation PV = nRT. This law is fundamental in understanding the behavior of gases under various conditions, particularly when analyzing processes like heating or cooling at constant pressure.
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Constant Pressure Process

In a constant pressure process, the pressure of the gas remains unchanged while its temperature and volume may vary. This is significant in thermodynamics as it allows for the calculation of work done by or on the gas, and it influences the shape of the pV-diagram, which typically shows a horizontal line for constant pressure.
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pV-Diagram

A pV-diagram is a graphical representation of the relationship between pressure (p) and volume (V) for a gas. In this diagram, the area under the curve represents work done during the process, and the shape of the curve can indicate whether the process is isothermal, isobaric, or adiabatic, providing insights into the thermodynamic behavior of the gas.
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Related Practice
Textbook Question
CALC The temperature of 0.150 mol of an ideal gas is held constant at 77.0°C while its volume is reduced to 25.0% of its initial volume. The initial pressure of the gas is 1.25 atm. (c) Does the gas exchange heat with its surroundings? If so, how much? Does the gas absorb or liberate heat?
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Textbook Question
Two moles of an ideal gas are heated at constant pressure from T = 27°C to T = 107°C. (b) Calculate the work done by the gas
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Textbook Question
A gas undergoes two processes. In the first, the volume remains constant at 0.200 m^3 and the pressure increases from 2.00 * 10^5 Pa to 5.00 * 10^5 Pa. The second process is a compression to a volume of 0.120 m^3 at a constant pressure of 5.00 * 10^5 Pa. (b) Find the total work done by the gas during both processes.
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Textbook Question
A gas undergoes two processes. In the first, the volume remains constant at 0.200 m^3 and the pressure increases from 2.00 * 10^5 Pa to 5.00 * 10^5 Pa. The second process is a compression to a volume of 0.120 m^3 at a constant pressure of 5.00 * 10^5 Pa. (a) In a pV-diagram, show both processes.
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Textbook Question
. BIO Work Done by the Lungs. The graph in Fig. E19.4 shows a pV-diagram of the air in a human lung when a person is inhaling and then exhaling a deep breath. Such graphs, obtained in clinical practice, are normally somewhat curved, but we have modeled one as a set of straight lines of the same general shape. (Important: The pressure shown is the gauge pressure, not the absolute pressure.) (b) The process illustrated here is somewhat different from those we have been studying, because the pressure change is due to changes in the amount of gas in the lung, not to temperature changes. (Think of your own breathing. Your lungs do not expand because they've gotten hot.) If the temperature of the air in the lung remains a reasonable 20°C, what is the maximum number of moles in this person's lung during a breath?
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