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Ch 20: The Micro/Macro Connection
Chapter 20, Problem 20

5.0 x 10²³ nitrogen molecules collide with a 10 cm² wall each second. Assume that the molecules all travel with a speed of 400 m/s and strike the wall head-on. What is the pressure on the wall?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Pressure

Pressure is defined as the force exerted per unit area. In the context of gas molecules colliding with a surface, it can be calculated using the formula P = F/A, where P is pressure, F is the total force from the collisions, and A is the area of the wall. Understanding pressure is crucial for analyzing how gas molecules interact with surfaces.
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Momentum Transfer

When gas molecules collide with a wall, they transfer momentum to the wall, which contributes to the force exerted on it. The change in momentum during a collision can be calculated using the formula Δp = mv, where m is the mass of the molecule and v is its velocity. This concept is essential for determining the total force from multiple collisions.
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Ideal Gas Behavior

Ideal gas behavior assumes that gas molecules are point particles that do not interact except during elastic collisions. This simplification allows for the application of kinetic theory to derive relationships between pressure, volume, and temperature. Understanding this concept helps in applying the ideal gas law and calculating pressure in scenarios involving gas molecules.
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Related Practice
Textbook Question
A water molecule has its three atoms arranged in a 'V' shape, so it has rotational kinetic energy around any of three mutually perpendicular axes. However, like diatomic molecules, its vibrational modes are not active at temperatures below 1000 K. What is the thermal energy of 2.0 mol of steam at a temperature of 160°C?
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Textbook Question
The rms speed of the molecules in 1.0 g of hydrogen gas is 1800 m/s. c. 500 J of work are done to compress the gas while, in the same process, 1200 J of heat energy are transferred from the gas to the environment. Afterward, what is the rms speed of the molecules?
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Textbook Question
At 100℃ the rms speed of nitrogen molecules is 576 m/s. Nitrogen at 100℃ and a pressure of 2.0 atm is held in a container with a 10 cm x 10 cm square wall. Estimate the rate of molecular collisions (collisions/s) on this wall.
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Textbook Question
a. What is the total rotational kinetic energy of 1.0 mol of nitrogen gas at 300 K?
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Textbook Question
b. A nitrogen molecule consists of two nitrogen atoms separated by 0.11 nm, the bond length. Treat the molecule as a rotating dumbbell and find the rms angular velocity at this temperature of a nitrogen molecule around the z-axis, as shown in Figure 20.10.
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Textbook Question
The 2010 Nobel Prize in Physics was awarded for the discovery of graphene, a two-dimensional form of carbon in which the atoms form a two-dimensional crystal-lattice sheet only one atom thick. Predict the molar specific heat of graphene. Give your answer as a multiple of R.
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