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Ch.2 Atoms and the Periodic Table
Chapter 2, Problem 51

Why does the fourth period in the periodic table contain 18 elements?

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1
Understand that the periodic table is organized by increasing atomic number and electron configuration.
Recognize that the fourth period begins with potassium (K) and ends with krypton (Kr).
Recall that the fourth period includes the filling of the 4s, 3d, and 4p orbitals.
Note that the 4s orbital can hold 2 electrons, the 3d orbital can hold 10 electrons, and the 4p orbital can hold 6 electrons.
Add the maximum number of electrons that can be held in these orbitals: 2 (4s) + 10 (3d) + 6 (4p) = 18 electrons, corresponding to 18 elements in the fourth period.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Periodic Table Structure

The periodic table is organized by increasing atomic number, with elements arranged in rows called periods. Each period corresponds to the filling of electron shells, which determines the chemical properties of the elements. The fourth period begins with potassium (atomic number 19) and ends with krypton (atomic number 36), encompassing 18 elements as it fills the 4s, 3d, and 4p subshells.
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Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. For the fourth period, the filling of the 4s orbital occurs first, followed by the 3d and 4p orbitals. This configuration explains why there are 18 elements in this period, as it includes all the elements that can be formed with the available orbitals in that energy level.
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Subshells and Their Capacity

Subshells are divisions of electron shells that can hold a specific number of electrons. The 4s subshell can hold 2 electrons, the 3d subshell can hold 10 electrons, and the 4p subshell can hold 6 electrons. Therefore, the total capacity for the fourth period is 2 (4s) + 10 (3d) + 6 (4p) = 18 electrons, which corresponds to the 18 elements found in this period.
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