Consider these two gas-phase reactions: a. AA(g) + BB(g) → 2 AB(g) b. AB(g) + CD(g) → AC(g) + BD(g) If the reactions have identical activation barriers and are carried out under the same conditions, which one would you expect to have the faster rate?
Consider this three-step mechanism for a reaction:
Cl2 (g) k1⇌k2 2 Cl (g) Fast
Cl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) Slow
Cl (g) + CCl3 (g) →k4 CCl4 (g) Fast
a. What is the overall reaction?
Verified Solution
Key Concepts
Reaction Mechanism
Elementary Steps
Overall Reaction
Which of these two reactions would you expect to have the smaller orientation factor? Explain. a. O(g) + N2(g) → NO( g) + N(g) b. NO(g) + Cl2(g) → NOCl( g) + Cl(g)
Consider this overall reaction, which is experimentally observed to be second order in AB and zero order in C: AB + C → A + BC Is the following mechanism valid for this reaction? AB + AB →k1 AB2 + A Slow AB2 + C → k2 AB + BC Fast
Consider this three-step mechanism for a reaction:
Cl2 (g) k1⇌k2 2 Cl (g) Fast
Cl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) Slow
Cl (g) + CCl3 (g) →k4 CCl4 (g) Fast
c. What is the predicted rate law?
Consider this two-step mechanism for a reaction: NO2(g) + Cl2(g) → k1 ClNO2(g) + Cl g) Slow NO2(g) + Cl(g) →k2 ClNO2(g) Fast b. Identify the intermediates in the mechanism.
Many heterogeneous catalysts are deposited on high-surfacearea supports. Why?