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Ch.15 - Chemical Kinetics
Chapter 15, Problem 85

Many heterogeneous catalysts are deposited on high-surfacearea supports. Why?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Heterogeneous Catalysis

Heterogeneous catalysis involves reactions where the catalyst is in a different phase than the reactants, typically solid catalysts interacting with gaseous or liquid reactants. This type of catalysis is advantageous because it allows for easier separation of the catalyst from the products and can enhance reaction rates due to increased surface area for reactant interaction.
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Surface Area and Reaction Rate

The surface area of a catalyst is crucial because it determines the amount of active sites available for reactants to interact. A higher surface area increases the likelihood of collisions between reactants and the catalyst, thereby enhancing the overall reaction rate. This is why catalysts are often supported on materials with high surface areas.
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Support Materials in Catalysis

Support materials are substances onto which catalysts are deposited to improve their effectiveness and stability. High-surface-area supports, such as activated carbon or alumina, provide a large area for the catalyst to adhere to, which not only maximizes catalytic activity but also helps in distributing the catalyst evenly, preventing sintering and deactivation during reactions.
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Related Practice
Textbook Question

Consider this three-step mechanism for a reaction:

Cl2 (g) k1⇌k2 2 Cl (g) Fast

Cl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) Slow

Cl (g) + CCl3 (g) →k4 CCl4 (g) Fast

a. What is the overall reaction?

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Textbook Question

Consider this three-step mechanism for a reaction:

Cl2 (g) k1⇌k2 2 Cl (g) Fast

Cl (g) + CHCl3 (g) →k3 HCl (g) + CCl3 (g) Slow

Cl (g) + CCl3 (g) →k4 CCl4 (g) Fast

c. What is the predicted rate law?

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Textbook Question

Consider this two-step mechanism for a reaction: NO2(g) + Cl2(g) → k1 ClNO2(g) + Cl g) Slow NO2(g) + Cl(g) →k2 ClNO2(g) Fast b. Identify the intermediates in the mechanism.

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Textbook Question

Suppose that the reaction A¡products is exothermic and has an activation barrier of 75 kJ/mol. Sketch an energy diagram showing the energy of the reaction as a function of the progress of the reaction. Draw a second energy curve showing the effect of a catalyst.

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Textbook Question

The activation barrier for the hydrolysis of sucrose into glucose and fructose is 108 kJ/mol. If an enzyme increases the rate of the hydrolysis reaction by a factor of 1 million, how much lower must the activation barrier be when sucrose is in the active site of the enzyme? (Assume that the frequency factors for the catalyzed and uncatalyzed reactions are identical and a temperature of 25 °C.)

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Textbook Question

The tabulated data were collected for this reaction at 500 °C: CH3CN(g) → CH3NC( g) a. Determine the order of the reaction and the value of the rate constant at this temperature.

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