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Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory
Chapter 11, Problem 44

Each ball-and-stick model shows the electron and molecular geometry of a generic molecule. Explain what is wrong with each molecular geometry and provide the correct molecular geometry, given the number of lone pairs and bonding groups on the central atom. (c)
Ball-and-stick model of a sulfur molecule with fluorine atoms, illustrating incorrect molecular geometry.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

VSEPR Theory

Valence Shell Electron Pair Repulsion (VSEPR) Theory is a model used to predict the geometry of individual molecules based on the repulsion between electron pairs around a central atom. According to this theory, electron pairs, whether bonding or lone pairs, will arrange themselves to minimize repulsion, leading to specific molecular shapes.
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Lone Pairs vs. Bonding Pairs

In molecular geometry, lone pairs are non-bonding pairs of electrons that occupy space around the central atom, influencing its shape. Bonding pairs, on the other hand, are shared between atoms to form bonds. The presence of lone pairs can distort the ideal bond angles and alter the expected geometry of the molecule.
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Molecular Geometry vs. Electron Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms in a molecule, while electron geometry considers the spatial arrangement of all electron pairs, including lone pairs. Understanding the distinction is crucial, as the presence of lone pairs can lead to different molecular geometries than what would be predicted based solely on bonding pairs.
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