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Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory
Chapter 11, Problem 31

A molecule with the formula AB3 has a trigonal pyramidal geometry. How many electron groups are on the central atom (A)?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. It is determined by the number of bonding pairs and lone pairs of electrons around the central atom. In the case of AB3 with trigonal pyramidal geometry, the arrangement is influenced by the presence of lone pairs that repel bonding pairs, leading to a specific shape.
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Electron Groups

Electron groups include both bonding pairs of electrons (shared between atoms) and lone pairs (non-bonding electrons) around a central atom. The total number of electron groups determines the molecular geometry according to the VSEPR (Valence Shell Electron Pair Repulsion) theory. For a trigonal pyramidal shape, the central atom must have four electron groups.
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VSEPR Theory

VSEPR (Valence Shell Electron Pair Repulsion) theory is a model used to predict the geometry of molecules based on the repulsion between electron pairs. According to this theory, electron groups will arrange themselves as far apart as possible to minimize repulsion. In the case of AB3, the presence of one lone pair leads to a trigonal pyramidal shape, indicating that there are four electron groups around the central atom.
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