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Ch.6 - Gases
Chapter 6, Problem 79

Chlorine gas reacts with fluorine gas to form chlorine trifluoride. Cl2(g) + 3 F2(g) → 2 ClF3(g) A 2.00-L reaction vessel, initially at 298 K, contains chlorine gas at a partial pressure of 337 mmHg and fluorine gas at a partial pressure of 729 mmHg. Identify the limiting reactant. Determine the theoretical yield of ClF3 in grams.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Limiting Reactant

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. To identify the limiting reactant, one must compare the mole ratios of the reactants based on the balanced chemical equation and the initial amounts available. In this case, the stoichiometry of the reaction Cl2 + 3F2 → 2ClF3 will guide the analysis.
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Partial Pressure

Partial pressure is the pressure exerted by a single component of a gas mixture. According to Dalton's Law of Partial Pressures, the total pressure of a gas mixture is the sum of the partial pressures of each individual gas. In this question, the partial pressures of chlorine and fluorine gases are crucial for calculating the number of moles available for the reaction, which is necessary for determining the limiting reactant.
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Theoretical Yield

Theoretical yield is the maximum amount of product that can be produced from a given amount of reactants, assuming complete conversion and no losses. It is calculated using the stoichiometry of the balanced equation and the limiting reactant. Once the limiting reactant is identified, the theoretical yield of ClF3 can be determined by converting moles of the limiting reactant to grams using its molar mass.
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Related Practice
Textbook Question

Lithium reacts with nitrogen gas according to the reaction: 6 Li(s) + N2(g) → 2 Li3N(s) What mass of lithium (in g) reacts completely with 58.5 mL of N2 gas at STP?

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Textbook Question

Hydrogen gas (a potential future fuel) can be formed by the reaction of methane with water according to the equation: CH4(g) + H2O(g) → CO(g) + 3 H2(g) In a particular reaction, 25.5 L of methane gas (measured at a pressure of 732 torr and a temperature of 25 °C) mixes with 22.8 L of water vapor (measured at a pressure of 702 torr and a temperature of 125 °C). The reaction produces 26.2 L of hydrogen gas at STP. What is the percent yield of the reaction?

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Textbook Question

Ozone is depleted in the stratosphere by chlorine from CF3Cl according to this set of equations:

CF3Cl + UV light → CF3 + Cl

Cl + O3 → ClO + O2

O3 + UV light → O2 + O

ClO + O → Cl + O2

What total volume of ozone at a pressure of 25.0 mmHg and a temperature of 225 K is destroyed when all of the chlorine from 15.0 g of CF3Cl goes through 10 cycles of the given reactions?

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Textbook Question

Carbon monoxide gas reacts with hydrogen gas to form methanol. CO(g) + 2 H2(g) → CH3OH(g) A 1.50-L reaction vessel, initially at 305 K, contains carbon monoxide gas at a partial pressure of 232 mmHg and hydrogen gas at a partial pressure of 397 mmHg. Identify the limiting reactant. Determine the theoretical yield of methanol in grams.

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Textbook Question

Consider a 1.0-L sample of helium gas and a 1.0-L sample of argon gas, both at room temperature and atmospheric pressure. a. Do the atoms in the helium sample have the same average kinetic energy as the atoms in the argon sample?

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Textbook Question

A flask at room temperature contains exactly equal amounts (in moles) of nitrogen and xenon. a. Which of the two gases exerts the greater partial pressure?

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