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Ch.6 - Gases
Chapter 6, Problem 75

Automobile air bags inflate following a serious impact. The impact triggers the chemical reaction: 2 NaN3(s) → 2 Na(s) + 3 N2(g) If an automobile air bag has a volume of 11.8 L, what mass of NaN3 (in g) is required to fully inflate the air bag upon impact? Assume STP conditions.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the relationships between the quantities of substances involved in a reaction. In this case, the stoichiometric coefficients from the reaction of sodium azide (NaN3) provide the necessary ratios to calculate how much NaN3 is needed to produce a specific volume of nitrogen gas (N2) at standard temperature and pressure (STP).
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Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. At STP, one mole of an ideal gas occupies 22.4 liters. This law is essential for determining how many moles of nitrogen gas are produced from the decomposition of sodium azide, which can then be used to find the mass of NaN3 required for the airbag to inflate.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is crucial for converting between the mass of a substance and the number of moles. In this problem, knowing the molar mass of sodium azide (NaN3) allows us to calculate how many grams are needed based on the moles derived from the stoichiometric calculations and the Ideal Gas Law.
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Related Practice
Textbook Question

Consider the chemical reaction: 2 H2O(l) → 2 H2(g) + O2(g) What mass of H2O is required to form 1.4 L of O2 at a temperature of 315 K and a pressure of 0.957 atm?

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Textbook Question

CH3OH can be synthesized by the reaction: CO(g) + 2 H2(g) → CH3OH( g) What volume of H2 gas (in L), at 748 mmHg and 86 °C, is required to synthesize 25.8 g CH3OH? How many liters of CO gas, measured under the same conditions, are required?

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Textbook Question

Oxygen gas reacts with powdered aluminum according to the reaction: 4 Al(s) + 3 O2(g) → 2 Al2O3(s) What volume of O2 gas (in L), measured at 782 mmHg and 25 °C, completely reacts with 53.2 g Al?

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Textbook Question

Lithium reacts with nitrogen gas according to the reaction: 6 Li(s) + N2(g) → 2 Li3N(s) What mass of lithium (in g) reacts completely with 58.5 mL of N2 gas at STP?

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Textbook Question

Hydrogen gas (a potential future fuel) can be formed by the reaction of methane with water according to the equation: CH4(g) + H2O(g) → CO(g) + 3 H2(g) In a particular reaction, 25.5 L of methane gas (measured at a pressure of 732 torr and a temperature of 25 °C) mixes with 22.8 L of water vapor (measured at a pressure of 702 torr and a temperature of 125 °C). The reaction produces 26.2 L of hydrogen gas at STP. What is the percent yield of the reaction?

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Textbook Question

Ozone is depleted in the stratosphere by chlorine from CF3Cl according to this set of equations:

CF3Cl + UV light → CF3 + Cl

Cl + O3 → ClO + O2

O3 + UV light → O2 + O

ClO + O → Cl + O2

What total volume of ozone at a pressure of 25.0 mmHg and a temperature of 225 K is destroyed when all of the chlorine from 15.0 g of CF3Cl goes through 10 cycles of the given reactions?

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