List all the possible products for each alkane substitution reaction. (Assume monosubstitution.) b. CH3CH2CH3 + Cl2 → d.
Ch.22 - Organic Chemistry
Chapter 22, Problem 56a,c,d
Draw the correct structure for each compound. a. 2-hexene c. 4,4-dimethyl-2-hexene d. 3-ethyl-4-methyl-2-pentene
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Identify the parent chain: The name '3-ethyl-4-methyl-2-pentene' indicates that the parent chain is 'pentene', which is a five-carbon chain with a double bond.
Locate the double bond: The '2-pentene' part of the name tells us that the double bond is between the second and third carbon atoms in the chain.
Add substituents: The '3-ethyl' indicates an ethyl group (C2H5) is attached to the third carbon, and '4-methyl' indicates a methyl group (CH3) is attached to the fourth carbon.
Draw the carbon skeleton: Start by drawing a five-carbon chain with a double bond between the second and third carbons. Then, add the ethyl group to the third carbon and the methyl group to the fourth carbon.
Verify the structure: Ensure that all carbons have four bonds and that the substituents are correctly placed according to the IUPAC name.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
IUPAC Nomenclature
IUPAC nomenclature is a systematic method for naming organic chemical compounds. It provides rules for identifying the structure of a compound based on its name, including the longest carbon chain, substituents, and their positions. Understanding these rules is essential for accurately interpreting and drawing chemical structures.
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Rules for Naming Alkanes
Alkenes and Double Bonds
Alkenes are hydrocarbons that contain at least one carbon-carbon double bond. The presence of a double bond affects the geometry and reactivity of the molecule. In the case of 3-ethyl-4-methyl-2-pentene, recognizing the position of the double bond is crucial for drawing the correct structure, as it influences the overall shape and properties of the compound.
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Rules for Naming Alkenes
Structural Isomers
Structural isomers are compounds that have the same molecular formula but different arrangements of atoms. In the context of alkenes, the position of substituents and the double bond can lead to different structural isomers. Understanding how to identify and draw these variations is important for accurately representing compounds like 3-ethyl-4-methyl-2-pentene.
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Isomers
Related Practice
Textbook Question
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Textbook Question
List all the possible products for each alkane substitution reaction. (Assume monosubstitution.) a.CH4 +Cl2 → b. CH3CH2Br + Br2 → d. CH3CHBr2 + Br2 →
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Textbook Question
Based on the molecular formula, determine whether each compound is an alkane, alkene, or alkyne. (Assume that the hydrocarbons are noncyclical and there is no more than one multiple bond.) a. C5H12 b. C3H6 c. C7H12 d. C11H22
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Textbook Question
Based on the molecular formula, determine whether each com- pound is an alkane, alkene, or alkyne. (Assume that the hydro- carbons are noncyclical and there is no more than one multiple bond.)
a. C8H16 b. C4H6 c. C7H16 d. C2H2
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Textbook Question
Write structural formulas for each of the nine structural isomers of heptane.
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