Chapter 19, Problem 48d
Predict the conditions (high temperature, low temperature, all temperatures, or no temperatures) under which each reaction is spontaneous. d. 2 NO2(g) → 2 NO(g) + O2(g) (endothermic)
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Given the values of ΔH°rxn, ΔS°rxn, and T, determine ΔSuniv and predict whether or not each reaction is spontaneous. (Assume that all reactants and products are in their standard states.) c. ΔH°rxn = +95 kJ; ΔS°rxn = -157 J/K; T = 298 K
Calculate the free energy change for this reaction at 25 °C. Is the reaction spontaneous? (Assume that all reactants and products are in their standard states.) 2 Ca(s) + O2( g) → 2 CaO(s) ΔH° rxn = -1269.8 kJ; ΔS° rxn = -364.6 J/K
Fill in the blanks in the table. Both ΔH and ΔS refer to the system.
How does the molar entropy of a substance change with increasing temperature?
For each pair of substances, choose the one that you expect to have the higher standard molar entropy (S°) at 25 °C. Explain your choices. e. NO2( g); CH3CH2CH3( g)
Rank each set of substances in order of increasing standard molar entropy (S°). Explain your reasoning. a. NH3(g); Ne(g); SO2(g); CH3CH2OH(g); He(g)