Skip to main content
Ch.18 - Aqueous Ionic Equilibrium
Chapter 18, Problem 111

Use the appropriate values of Ksp and Kf to find the equilibrium constant for the reaction. FeS(s) + 6 CN-(aq) ⇌ Fe(CN)64-(aq) + S2-(aq)

Verified Solution

Video duration:
3m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Solubility Product Constant (Ksp)

The solubility product constant (Ksp) is an equilibrium constant that applies to the solubility of sparingly soluble ionic compounds. It quantifies the extent to which a compound can dissolve in water, represented by the concentrations of its ions at equilibrium. For the reaction involving FeS, Ksp helps determine the solubility of FeS in the presence of complexing agents like CN-.
Recommended video:
Guided course
01:47
Solubility Product Constant

Formation Constant (Kf)

The formation constant (Kf) is a measure of the stability of a complex ion in solution. It quantifies the equilibrium between the free ions and the complex formed when they react. In the given reaction, Kf is crucial for understanding how effectively CN- ions bind with Fe2+ to form the complex ion Fe(CN)64-, influencing the overall equilibrium of the reaction.
Recommended video:
Guided course
02:20
Complex Ions and Formation Constant

Equilibrium Constant (K)

The equilibrium constant (K) for a reaction is derived from the concentrations of the products and reactants at equilibrium. It provides insight into the extent of the reaction and can be calculated using Ksp and Kf values. In this case, the equilibrium constant for the reaction involving FeS and CN- can be determined by combining the Ksp of FeS and the Kf for the formation of the complex ion, reflecting the relationship between solubility and complexation.
Recommended video:
Guided course
01:14
Equilibrium Constant K
Related Practice
Textbook Question

A solution is 0.010 M in Ba2+ and 0.020 M in Ca2+. a. If sodium sulfate is used to selectively precipitate one of the cations while leaving the other cation in solution, which cation will precipitate first? What minimum concentration of Na2SO4 will trigger the precipitation of the cation that precipitates first?

1308
views
1
rank
Textbook Question

A solution is 0.010 M in Ba2+ and 0.020 M in Ca2+. b. What is the remaining concentration of the cation that precipitates first, when the other cation begins to precipitate?

1213
views
Textbook Question

A solution is made 1.1⨉10-3 M in Zn(NO3)2 and 0.150 M in NH3. After the solution reaches equilibrium, what concentration of Zn2+(aq) remains?

1060
views
Textbook Question

A 1.0-L buffer solution initially contains 0.25 mol of NH3 and 0.25 mol of NH4Cl. In order to adjust the buffer pH to 8.75, should you add NaOH or HCl to the buffer mixture? What mass of the correct reagent should you add?

2806
views
Textbook Question

In analytical chemistry, bases used for titrations must often be standardized; that is, their concentration must be precisely determined. Standardization of sodium hydroxide solutions can be accomplished by titrating potassium hydrogen phthalate (KHC8H4O4), also known as KHP, with the NaOH solution to be standardized. b. The titration of 0.5527 g of KHP required 25.87 mL of an NaOH solution to reach the equivalence point. What is the concentration of the NaOH solution?

868
views
Textbook Question

A 5.55-g sample of a weak acid with Ka = 1.3⨉10-4 was combined with 5.00 mL of 6.00 M NaOH, and the resulting solution was diluted to 750.0 mL. The measured pH of the solution was 4.25. What is the molar mass of the weak acid?

996
views
2
comments