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Ch.18 - Aqueous Ionic Equilibrium
Chapter 18, Problem 119

In analytical chemistry, bases used for titrations must often be standardized; that is, their concentration must be precisely determined. Standardization of sodium hydroxide solutions can be accomplished by titrating potassium hydrogen phthalate (KHC8H4O4), also known as KHP, with the NaOH solution to be standardized. b. The titration of 0.5527 g of KHP required 25.87 mL of an NaOH solution to reach the equivalence point. What is the concentration of the NaOH solution?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. It involves the gradual addition of a titrant (a solution of known concentration) to a sample until a reaction reaches its equivalence point, where the amount of titrant equals the amount of substance in the sample. This method is commonly used in acid-base reactions to find the concentration of an unknown solution.
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Equivalence Point

The equivalence point in a titration is the stage at which the amount of titrant added is stoichiometrically equivalent to the amount of substance present in the sample. At this point, the reaction between the titrant and the analyte is complete, and it is often indicated by a color change in the solution due to an indicator. Understanding the equivalence point is crucial for accurately calculating the concentration of the unknown solution.
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Molarity

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is expressed in units of moles per liter (mol/L). In the context of titration, calculating the molarity of the titrant (in this case, NaOH) is essential for determining how much of the titrant is needed to completely react with a known amount of the analyte (KHP), allowing for the standardization of the solution.
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