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Ch.6 - Thermochemistry
Chapter 6, Problem 112

When 10.00 g of phosphorus is burned in O2(g) to form P4O10(s), enough heat is generated to raise the temperature of 2950 g of water from 18.0 °C to 38.0 °C. Calculate the enthalpy of formation of P4O10(s) under these conditions.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Enthalpy of Formation

The enthalpy of formation is the heat change that occurs when one mole of a compound is formed from its elements in their standard states. It is a crucial concept in thermodynamics and is typically expressed in kilojoules per mole (kJ/mol). Understanding this concept is essential for calculating the energy changes associated with chemical reactions, such as the combustion of phosphorus to form P4O10.
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Calorimetry

Calorimetry is the science of measuring the heat of chemical reactions or physical changes. In this context, it involves calculating the heat absorbed by water when phosphorus is burned, using the formula q = mcΔT, where q is the heat absorbed, m is the mass of the water, c is the specific heat capacity, and ΔT is the change in temperature. This measurement is vital for determining the enthalpy change of the reaction.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to relate the amount of phosphorus burned to the amount of P4O10 produced. In this problem, stoichiometry is necessary to convert the heat calculated from the calorimetry into the enthalpy of formation per mole of P4O10, ensuring accurate results.
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Related Practice
Open Question
One tablespoon of peanut butter has a mass of 16 g. It is combusted in a calorimeter whose heat capacity is 120.0 kJ/°C. The temperature of the calorimeter rises from 22.2 °C to 25.4 °C. Find the food caloric content of peanut butter.
Textbook Question

A mixture of 2.0 mol of H2(g) and 1.0 mol of O2(g) is placed in a sealed evacuated container made of a perfect insulating material at 25 °C. The mixture is ignited with a spark and reacts to form liquid water. Determine the temperature of the water.

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Textbook Question

A 20.0-L volume of an ideal gas in a cylinder with a piston is at a pressure of 3.0 atm. Enough weight is suddenly removed from the piston to lower the external pressure to 1.5 atm. The gas then expands at constant temperature until its pressure is 1.5 atm. Find w.

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Textbook Question

The ΔH for the oxidation of sulfur in the gas phase to SO3 is –204 kJ/mol and for the oxidation of SO2 to SO3 is 89.5 kJ/mol. Find the enthalpy of formation of SO2 under these conditions.

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Textbook Question

The ΔH°f of TiI3(s) is –328 kJ/mol and the ΔH ° for the reaction 2 Ti(s) + 3 I2(g) → 2 TiI3(s) is –839 kJ. Calculate the ΔH of sublimation of I2(s), which is a solid at 25 °C.

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Textbook Question

A gaseous fuel mixture contains 25.3% methane (CH4), 38.2% ethane (C2H6), and the rest propane (C3H8) by volume. When the fuel mixture contained in a 1.55 L tank, stored at 755 mmHg and 298 K, undergoes complete combustion, how much heat is emitted? (Assume that the water produced by the combustion is in the gaseous state.)

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