Chapter 6, Problem 111
A 20.0-L volume of an ideal gas in a cylinder with a piston is at a pressure of 3.0 atm. Enough weight is suddenly removed from the piston to lower the external pressure to 1.5 atm. The gas then expands at constant temperature until its pressure is 1.5 atm. Find w.
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Hydrogen and methanol have both been proposed as alternatives to hydrocarbon fuels. How does the energy of these fuels compare to that of octane (C8H18)?
Under certain nonstandard conditions, oxidation by O2( g) of 1 mol of SO2( g) to SO3( g) absorbs 89.5 kJ. The enthalpy of formation of SO3( g) is -204.2 kJ under these conditions. Find the enthalpy of formation of SO2( g).
A mixture of 2.0 mol of H2( g) and 1.0 mol of O2( g) is placed in a sealed evacuated container made of a perfect insulating material at 25 °C. The mixture is ignited with a spark and reacts to form liquid water. Determine the temperature of the water.
When 10.00 g of phosphorus is burned in O2( g) to form P4O10(s), enough heat is generated to raise the temperature of 2950 g of water from 18.0 °C to 38.0 °C. Calculate the enthalpy of formation of P4O10(s) under these conditions.
The ΔH for the oxidation of sulfur in the gas phase to SO3 is -204 kJ/mol and for the oxidation of SO2 to SO3 is 89.5 kJ/mol. Find the enthalpy of formation of SO2 under these conditions.
The ΔH °f of TiI3(s) is -328 kJ>mol and the ΔH ° for the reaction 2 Ti(s) + 3 I2( g)¡2 TiI3(s) is -839 kJ. Calculate the ΔH of sublimation of I2(s), which is a solid at 25 °C.