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Ch.6 - Thermochemistry
Chapter 6, Problem 103

A 25.5-g aluminum block is warmed to 65.4 °C and plunged into an insulated beaker containing 55.2 g water initially at 22.2 °C. The aluminum and the water are allowed to come to thermal equilibrium. Assuming that no heat is lost, what is the final temperature of the water and aluminum?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Thermal Equilibrium

Thermal equilibrium occurs when two substances at different temperatures come into contact and exchange heat until they reach the same temperature. In this scenario, the aluminum block and water will transfer heat between each other until they stabilize at a common final temperature, which is essential for solving the problem.
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Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of one gram of a substance by one degree Celsius. Each material has a unique specific heat capacity, which influences how much heat it can absorb or release. For this problem, the specific heat capacities of aluminum and water will be crucial in calculating the final temperature after heat exchange.
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Heat Transfer Equation

The heat transfer equation, often expressed as Q = mcΔT, relates the heat gained or lost (Q) to the mass (m), specific heat capacity (c), and change in temperature (ΔT) of a substance. In this case, the heat lost by the aluminum block will equal the heat gained by the water, allowing us to set up an equation to find the final equilibrium temperature.
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Related Practice
Textbook Question

Use standard enthalpies of formation to calculate the standard change in enthalpy for the melting of ice. (The ΔH°f for H2O(s) is –291.8 kJ/mol.)

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Textbook Question

Use standard enthalpies of formation to calculate the standard change in enthalpy for the melting of ice. (The ΔH°f for H2O(s) is –291.8 kJ/mol.) Use this value to calculate the mass of ice required to cool 355 mL of a beverage from room temperature (25.0 °C) to 0.0 °C. Assume that the specific heat capacity and density of the beverage are the same as those of water.

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Textbook Question

Dry ice is solid carbon dioxide. Instead of melting, solid carbon dioxide sublimes according to the equation: CO2(s) → CO2(g) ◀ When carbon dioxide sublimes, the gaseous CO2 is cold enough to cause water vapor in the air to condense, forming fog. When dry ice is added to warm water, heat from the water causes the dry ice to sublime more quickly. The evaporating carbon dioxide produces a dense fog often used to create special effects. In a simple dry ice fog machine, dry ice is added to warm water in a Styrofoam cooler. The dry ice produces fog until it evaporates away, or until the water gets too cold to sublime the dry ice quickly enough. Suppose that a small Styrofoam cooler holds 15.0 L of water heated to 85 °C. Use standard enthalpies of formation to calculate the change in enthalpy for dry ice sublimation, and calculate the mass of dry ice that should be added to the water so that the dry ice completely sublimes away when the water reaches 25 °C. Assume no heat loss to the surroundings. (The ΔH°f for CO2(s) is –427.4 kJ/mol.)

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Textbook Question

If 50.0 mL of ethanol (density = 0.789 g/mL) initially at 7.0 °C is mixed with 50.0 mL of water (density = 1.0 g/mL) initially at 28.4 °C in an insulated beaker, and assuming that no heat is lost, what is the final temperature of the mixture?

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Open Question
Calculate the caloric content of table sugar (sucrose, C12H22O11), given that the standard enthalpy of formation of sucrose is -2226.1 kJ/mol. For comparison, the standard enthalpy of formation of palmitic acid (C16H32O2), a dietary fat found in beef and butter, is -208 kJ/mol. Use H2O(l) in the balanced chemical equations, as the metabolism of these compounds produces liquid water.
Textbook Question

Palmitic acid (C16H32O2) is a dietary fat found in beef and butter. The caloric content of palmitic acid is typical of fats in general. Write a balanced equation for the complete combustion of palmitic acid and calculate the standard enthalpy of combustion. What is the caloric content of palmitic acid in Cal/g? The standard enthalpy of formation of palmitic acid is -208 kJ/mol and that of sucrose is -2226.1 kJ/mol. [Use H2O(l) in the balanced chemical equations because the metabolism of these compounds produces liquid water.]

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