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Ch.5 - Gases
Chapter 5, Problem 101

Consider the reaction: 2 NiO(s) → 2 Ni(s) + O2(g). If O2 is collected over water at 40.0 °C and a total pressure of 745 mmHg, what volume of gas is collected for the complete reaction of 24.78 g of NiO?

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1
Calculate the molar mass of NiO by adding the atomic masses of Ni and O.
Determine the number of moles of NiO by dividing the given mass (24.78 g) by the molar mass of NiO.
Use the stoichiometry of the balanced chemical equation to find the moles of O2 produced. According to the equation, 2 moles of NiO produce 1 mole of O2.
Use the ideal gas law, PV = nRT, to calculate the volume of O2. First, convert the temperature from Celsius to Kelvin by adding 273.15.
Adjust the total pressure to account for the vapor pressure of water at 40.0 °C, then use the adjusted pressure in the ideal gas law to find the volume of O2.
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