A gaseous hydrogen- and carbon-containing compound is decomposed and found to contain 82.66% carbon and 17.34% hydrogen by mass. The mass of 158 mL of the gas, measured at 556 mmHg and 25 °C, was 0.275 g. What is the molecular formula of the compound?
Ch.5 - Gases
Chapter 5, Problem 102
Consider the reaction: 2 Ag2O(s) → 4 Ag(s) + O2(g) If this reaction produces 15.8 g of Ag(s), what total volume of gas can be collected over water at a temperature of 25 °C and a total pressure of 752 mmHg?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Stoichiometry
Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced equation. It allows us to determine the amount of substances consumed and produced in a reaction. In this case, knowing the amount of silver produced helps us find the moles of oxygen gas generated, which is essential for further calculations.
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Ideal Gas Law
The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law is crucial for calculating the volume of gas produced in the reaction. By rearranging the equation, we can solve for volume when we know the number of moles of gas and the conditions of temperature and pressure.
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Dalton's Law of Partial Pressures
Dalton's Law states that the total pressure of a gas mixture is equal to the sum of the partial pressures of each individual gas. When collecting gas over water, the vapor pressure of water must be considered. This means that the pressure of the gas collected must be adjusted by subtracting the vapor pressure of water at the given temperature to find the pressure of the dry gas.
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Related Practice
Textbook Question
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Textbook Question
A gaseous hydrogen- and carbon-containing compound is decomposed and found to contain 85.63% C and 14.37% H by mass. The mass of 258 mL of the gas, measured at STP, was 0.646 g. What is the molecular formula of the compound?
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Open Question
Consider the reaction: 2 NiO(s) → 2 Ni(s) + O2(g). If O2 is collected over water at 40.0 °C and a total pressure of 745 mmHg, what volume of gas is collected for the complete reaction of 24.78 g of NiO?
Open Question
When hydrochloric acid is poured over potassium sulfide, 42.9 mL of hydrogen sulfide gas is produced at a pressure of 752 torr and 25.8 °C. Write an equation for the gas-evolution reaction. Determine how much potassium sulfide (in grams) reacted.
Textbook Question
Consider the reaction:
2 SO2(g) + O2(g) → 2 SO3(g)
a. If 285.5 mL of SO2 reacts with 158.9 mL of O2 (both measured at 315 K and 50.0 mmHg), what is the limiting reactant and the theoretical yield of SO3?
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Textbook Question
Consider the reaction:
2 SO2(g) + O2(g) → 2 SO3(g)
b. If 187.2 mL of SO3 is collected (measured at 315 K and 50.0 mmHg), what is the percent yield for the reaction?