A Cu/Cu2+ concentration cell has a voltage of 0.22 V at 25 °C. The concentration of Cu2+ in one of the half-cells is 1.5×10–3 M. What is the concentration of Cu2+ in the other half-cell? (Assume the concentration in the unknown cell is the lower of the two concentrations.)
Ch.19 - Electrochemistry
Chapter 19, Problem 85
Refer to the tabulated values of ∆Gf° in Appendix IIB to calculate E°cell for a fuel cell that employs the reaction between methane gas (CH4) and oxygen to form carbon dioxide and gaseous water.
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1
Identify the balanced chemical equation for the reaction: CH_4(g) + 2O_2(g) \rightarrow CO_2(g) + 2H_2O(g).
Use the standard Gibbs free energy of formation (∆G_f°) values from Appendix IIB for each species involved in the reaction: CH_4(g), O_2(g), CO_2(g), and H_2O(g).
Calculate the standard Gibbs free energy change (∆G°) for the reaction using the formula: ∆G° = Σ(∆G_f° of products) - Σ(∆G_f° of reactants).
Use the relationship between Gibbs free energy change and cell potential: ∆G° = -nFE°_cell, where n is the number of moles of electrons transferred and F is the Faraday constant.
Solve for the standard cell potential (E°_cell) using the equation: E°_cell = -∆G° / (nF).
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