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Ch.13 - Solutions
Chapter 13, Problem 103

A saturated solution forms when 0.0537 L of argon, at a pressure of 1.0 atm and temperature of 25 °C, is dissolved in 1.0 L of water. Calculate the Henry's law constant for argon.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Henry's Law

Henry's Law states that the amount of gas that dissolves in a liquid at a given temperature is directly proportional to the partial pressure of that gas above the liquid. This relationship can be expressed mathematically as C = kH * P, where C is the concentration of the gas in the liquid, kH is the Henry's law constant, and P is the partial pressure of the gas.
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Saturation Concentration

A saturated solution is one in which the maximum amount of solute has been dissolved in the solvent at a specific temperature and pressure. In the context of gases, this means that the concentration of the gas in the liquid phase is at its limit, and any additional gas will not dissolve but will remain in the gaseous phase.
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Units of Henry's Law Constant

The Henry's law constant (kH) can be expressed in various units depending on the context, such as mol/(L·atm) or atm/(mol/L). Understanding the units is crucial for correctly calculating and interpreting the constant, as it relates the concentration of the dissolved gas to its partial pressure in the gas phase.
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Related Practice
Textbook Question

The solubility of carbon tetrachloride (CCl4) in water at 25 °C is 1.2 g/L. The solubility of chloroform (CHCl3) at the same temperature is 10.1 g/L. Why is chloroform almost ten times more soluble in water than carbon tetrachloride?

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Open Question
Potassium perchlorate (KClO4) has a lattice energy of -599 kJ/mol and a heat of hydration of -548 kJ/mol. Find the heat of solution for potassium perchlorate and determine the temperature change that occurs when 10.0 g of potassium perchlorate is dissolved with enough water to make 100.0 mL of solution. (Assume a heat capacity of 4.05 J/g°C for the solution and a density of 1.05 g/mL.)
Textbook Question

Sodium hydroxide (NaOH) has a lattice energy of -887 kJ/mol and a heat of hydration of -932 kJ/mol. How much solution could be heated to boiling by the heat evolved by the dissolution of 25.0 g of NaOH? (For the solution, assume a heat capacity of 4.0 J/g·°C, an initial temperature of 25.0 °C, a boiling point of 100.0 °C, and a density of 1.05 g/mL.)

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Textbook Question

A gas has a Henry's law constant of 0.112 M>atm. What total volume of solution is needed to completely dissolve 1.65 L of the gas at a pressure of 725 torr and a temperature of 25 °C?

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Textbook Question

The Safe Drinking Water Act (SDWA) sets a limit for mercury—a toxin to the central nervous system—at 0.0020 ppm by mass. Water suppliers must periodically test their water to ensure that mercury levels do not exceed this limit. Suppose water becomes contaminated with mercury at twice the legal limit (0.0040 ppm). How much of this water would a person have to consume to ingest 50.0 mg of mercury?

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Textbook Question

Water softeners often replace calcium ions in hard water with sodium ions. Since sodium compounds are soluble, the presence of sodium ions in water does not cause the white, scaly residues caused by calcium ions. However, calcium is more beneficial to human health than sodium because calcium is a necessary part of the human diet, while high levels of sodium intake are linked to increases in blood pressure. The U.S. Food and Drug Administration (FDA) recommends that adults ingest less than 2.4 g of sodium per day. How many liters of softened water, containing a sodium concentration of 0.050% sodium by mass, would a person have to consume to exceed the FDA recommendation? (Assume a water density of 1.0 g/mL.)

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