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Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 55

Why does spilling room-temperature water over your skin on a hot day cool you down while spilling room-temperature vegetable oil does not?

Verified step by step guidance
1
Understand that the cooling effect of water is primarily due to the process of evaporation. When water evaporates, it absorbs heat from the surroundings (in this case, your skin) to change from a liquid to a gas, which cools the surface.
Recognize that water has a high heat of vaporization, meaning it requires a significant amount of energy to evaporate. This energy is taken from your skin, thus cooling it down.
Consider the properties of vegetable oil. Unlike water, vegetable oil has a much lower tendency to evaporate at room temperature because it has a higher boiling point and lower vapor pressure.
Since vegetable oil does not evaporate easily, it does not absorb heat from your skin in the same way water does. Therefore, it does not provide the same cooling effect.
Conclude that the key difference lies in the evaporation process: water evaporates readily at room temperature, absorbing heat and cooling the skin, while vegetable oil does not.