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Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory

Chapter 10, Problem 45c

Determine the geometry about each interior atom in each molecule and sketch the molecule. (Skeletal structure is indicated in parentheses.) c. H2O2 (HOOH)

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Hey everyone today, we've been given the chemical formula and skeletal structure of a compound and were asked to draw the Lewis structure and identified the geometry of each internal atom. So first things first to draw out the Lewis structure. The very first step is to identify how many valence electrons are present within the compound. Carbon is a group for molecule I'm sorry, Group for element which means it will have four valence electrons And we have four carbons hydrogen is the very first element and it will have one valence electron and we have 10 of those. Finally, oxygen is a group six element. It has £6 electrons and we have two of those adding it all up. We get 16 plus 10 plus Or 38 total valence electrons. Now that we have the valence electrons, I'd like to really quickly go back and take a look at this council structure because this will help us right out our drought or lewis structure. Here we see we have a central carbon that is bonded to three metal groups, three CH 3 groups. And to that same central carbon, it is also directly bonded to an O. H. Or sorry to an O. An oxidant which itself is then bonded to an O. H. Group. So with that in mind let's go ahead and start drawing, we have a central carbon. It is attached to three carbons itself and to an O. Which is also connected to another O. Another oxygen. And finally that is to a hydrogen. And each of these external or yeah external carbons are attached to hydrogen themselves. H. H. H. H. And H. Now let's count up how many valence electrons we have so far. We have eight here, hate here and eight here. So that brings us to 24. Then we also have 26, and 30. Remember each single Bond has two electrons in it. However, We've only reached 30 valence electrons. We still need the other eight. This can be really easily added as lone pairs to each of the oxygen's. So this fulfills their octet and We reach our total of eight or 38 valence electrons now to find the geometry of each internal atom. The internal atoms being the oxygen's and the carbons. Well, we can actually group them by element. Now each carbon has four bonds, Right? Each carbon is bonded towards four other molecules. It has no lone pairs. So let's write that out. Carbon has four bonds, four bonds and zero lone pairs. Zero piece. This means that each carbon will have a tetra hydro geometry. It'll look essentially like a plus. It'll be plainer. It'll be within the plane not pointing out in any odd directions. So this will have a tetrahedron geometry. Tetra he drill. And let me just change it to blue. Where is she? Uh How about green? Yeah, we'll change that to green for the oxygen's though. It gets a little trickier. She eats oxygen as two lone pairs. Right? So and each oxygen has two bonds. So let's write that out. Oxygen has two bonds for each and two lone pairs piers. So let's draw that out. Oxygen has two lone pairs and two bonds, while the lone pairs will cause it to bend. So, in other words, and we'll just put R and R. For any any molecule period. So because of this, because of the repulsion that is being induced by these lone pairs, oxygen or oxygen has a bent geometry, it'll be bent. So therefore the geometry for the carbons will all be tetrahedron. The geometry for both oxygen's will be bent. I hope this helps. And I look forward to seeing you on the next one.