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Ch.12 - Solids and Modern Material
Chapter 12, Problem 62

How many molecular orbitals are present in the valence band of a sodium crystal with a mass of 5.45 g?

Verified step by step guidance
1
Determine the number of moles of sodium in the given mass using the formula: \( \text{moles} = \frac{\text{mass}}{\text{molar mass}} \). The molar mass of sodium (Na) is approximately 22.99 g/mol.
Calculate the number of sodium atoms using Avogadro's number (\(6.022 \times 10^{23}\) atoms/mol). Multiply the number of moles by Avogadro's number to find the total number of sodium atoms.
Understand that in a sodium crystal, each sodium atom contributes one valence electron to the formation of molecular orbitals in the valence band.
Recognize that the number of molecular orbitals in the valence band is equal to the number of valence electrons, which is the same as the number of sodium atoms in the crystal.
Conclude that the number of molecular orbitals in the valence band is equal to the number of sodium atoms calculated in step 2.