Skip to main content
Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure

Chapter 8, Problem 49

What bond angles do you expect for each of the following? (d) The O¬B¬O angle in BO33-

Verified Solution
Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Video transcript

Hey everyone, we're asked what is the expected bond angle for the oxygen arsenic? Oxygen bond in RC. Right first, let's go ahead and determine the total number of electrons will have in our lewis structure. Starting with our arsenic, we know that this is in our group five A. So this will have five valence electrons since we have only one of arsenic will multiply it by one to get a total of five. Now looking at our oxygen, we know that this is in our group six A. So this will have six valence electrons since we have three of oxygen. We're going to multiply this by three to get a total of 18 electrons. And since we have that -3 charge, this means that we will have to add plus three electrons. So in total we will need to draw out 26 electrons. Now let's go ahead and draw this out. Starting with arsenic, we know that this is our central atom since it is the least electro negative atom and we're going to connect our three oxygen's. And to complete those 26 electrons, we end up with three lone pairs on each oxygen And each oxygen will also have a formal charge of -1. As we can see right here, we have three electron groups surrounding our arsenic which is three atoms and zero lone pairs. So this means that we have a tribunal planer geometry And our bond angle is going to be 120° for our oxygen arsenic, oxygen bond and this is going to be our final answer. Now, I hope that made sense and let us know if you have any questions.
Related Practice
Textbook Question
What geometric arrangement of charge clouds do you expect for atoms that have the following number of charge clouds? (a) 3 (b) 5 (c) 2 (d) 6
510
views
Textbook Question
What shape do you expect for molecules that meet the following descriptions? (a) A central atom with two lone pairs and three bonds to other atoms (b) A central atom with two lone pairs and two bonds to other atoms (c) A central atom with two lone pairs and four bonds to other atoms
603
views
Textbook Question
How many charge clouds are there around the central atom in molecules that have the following geometry? (a) Tetrahedral (b) Octahedral (c) Bent (d) Linear (e) Square pyramidal (f) Trigonal pyramidal
799
views
Textbook Question
Oceanographers study the mixing of water masses by releasing tracer molecules at a site and then detecting their presence at other places. The molecule trifluoromethylsulfur pentafluoride is one such tracer. Draw an electron-dot structure for CF3SF5, and predict the bond angles around both carbon and sulfur.
410
views
Textbook Question
A potential replacement for the chlorofluorocarbon refrigerants that harm the Earth's protective ozone layer is a compound called E143a, or trifluoromethyl methyl ether, F3COCH3. Draw an electron-dot structure for F3COCH3, and predict the geometry around both the carbons and the oxygen.
367
views
Textbook Question
Like cyclohexane (Problem 8.54), benzene also contains a sixmembered ring of carbon atoms, but it is flat rather than puckered. Explain, and predict the values of the C¬C¬C bond angles.

347
views