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Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
Chapter 8, Problem 53

A potential replacement for the chlorofluorocarbon refrigerants that harm the Earth's protective ozone layer is a compound called E143a, or trifluoromethyl methyl ether, F3COCH3. Draw an electron-dot structure for F3COCH3, and predict the geometry around both the carbons and the oxygen.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron-Dot Structures

Electron-dot structures, also known as Lewis structures, represent the valence electrons of atoms within a molecule. They illustrate how atoms are bonded together and show the arrangement of electrons, including lone pairs. Understanding how to draw these structures is essential for predicting molecular geometry and reactivity.
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VSEPR Theory

Valence Shell Electron Pair Repulsion (VSEPR) theory is a model used to predict the geometry of molecules based on the repulsion between electron pairs surrounding a central atom. According to VSEPR, electron pairs will arrange themselves to minimize repulsion, leading to specific molecular shapes. This theory is crucial for determining the spatial arrangement of atoms in a molecule like trifluoromethyl methyl ether.
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Hybridization

Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate bonding in molecules. In the case of carbon and oxygen in F3COCH3, understanding hybridization helps predict the types of bonds formed and the geometry around each atom. For example, sp3 hybridization indicates tetrahedral geometry, while sp2 suggests trigonal planar arrangements.
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