Chapter 8, Problem 126
Bond vibrations for the symmetric and asymmetric stretch in methane are illustrated below. Decide whether each vibration will result in the absorption of IR radiation. Arrows indicate the movement of atoms during the vibration.
Video transcript
Cyclooctatetraene dianion, C8H82-, is an organic ion with the structure shown. Considering only the p bonds and not the s bonds, cyclooctatetraene dianion can be described by the following energy diagrams of its p molecular orbitals:
(b) Three of the p molecular orbitals are bonding, three are antibonding, and two are nonbonding, meaning that they have the same energy level as isolated p orbitals. Which is which?
Cyclooctatetraene dianion, C8H82-, is an organic ion with the structure shown. Considering only the p bonds and not the s bonds, cyclooctatetraene dianion can be described by the following energy diagrams of its p molecular orbitals:
(c) Complete the MO energy diagram by assigning the appropriate numbers of p electrons to the various molecular orbitals, indicating the electrons using up/down arrows 1c T2.