Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 133
X rays with a wavelength of 1.54 * 10-10 m are produced when a copper metal target is bombarded with high-energy electrons that have been accelerated by a voltage difference of 30,000 V. The kinetic energy of the electrons equals the product of the voltage difference and the electronic charge in coulombs, where 1 volt-coulomb = 1 J. (a) What is the kinetic energy in joules and the de Broglie wavelength in meters of an electron that has been accel-erated by a voltage difference of 30,000 V?
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Textbook Question
One watt (W) is equal to 1 J/s. Assuming that 5.0% of the energy output of a 75 W light bulb is visible light and that the average wavelength of the light is 550 nm, how many photons are emitted by the light bulb each second?
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Textbook Question
Microwave ovens work by irradiating food with microwave radiation, which is absorbed and converted into heat. Assum-ing that radiation with l = 15.0 cm is used, that all the energy is converted to heat, and that 4.184 J is needed to raise the temperature of 1.00 g of water by 1.00 °C, how many photons are necessary to raise the temperature of a 350 mL cup of water from 20 °C to 95 °C?
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Textbook Question
The amount of energy necessary to remove an electron from an atom is a quantity called the ionization energy, Ei. This energy can be measured by a technique called photoelectron spectroscopy, in which light of wavelength l is directed at an atom, causing an electron to be ejected. The kinetic energy of the ejected electron (Ek) is measured by determining its veloc-ity, v (Ek = mv2/2), and Ei is then calculated using the conservation of energy principle. That is, the energy of the incident light equals Ei plus Ek. What is the ionization energy of selenium atoms in kilojoules per mole if light with l = 48.2 nm produces electrons with a velocity of 2.371 * 106 m/s? The mass, m, of an electron is 9.109 * 10-31 kg.
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Textbook Question
In the Bohr model of atomic structure, electrons are constrained to orbit a nucleus at specific distances, given by the equation
where r is the radius of the orbit, Z is the charge on the nucleus, a0 is the Bohr radius and has a value of 5.292 * 10-11 m, and n is a positive integer (n = 1, 2, 3...) like a principal quantum number. Furthermore, Bohr concluded that the energy level E of an electron in a given orbit is where e is the charge on an electron. Derive an equation that will let you calculate the difference ∆E between any two energy levels. What relation does your equation have to the Balmer–Rydberg equation?
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Textbook Question
Assume that the rules for quantum numbers are different and that the spin quantum number ms can have any of three values, ms = -1/2, 0, +1/2, while all other rules remain the same.
(a) Draw an orbital-filling diagram for the element with Z = 25, showing the individual electrons in the outer-most subshell as up arrows, down arrows, or 0. How many partially filled orbitals does the element have?
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Textbook Question
A minimum energy of 7.21⨉10-19 J is required to produce the photoelectric effect in chromium metal. (a) What is the minimum frequency of light needed to remove an electron from chromium?
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