Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 56
Spectroscopy is a technique that uses the interaction of radiant energy with matter to identify or quantify a substance in a sample. A deuterium lamp is often used a light source in the ultraviolet region of the spectrum and the emission spectrum is shown. Is this a continuous or line emission spectrum?
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Textbook Question
The work function of calcium metal is kJ/mol, which corresponds to light with a wavelength of 432 nm. Which of the following will cause the largest number of electrons to be ejected from cesium?
(a) High-amplitude wave with a wavelength of 400 nm
(b) Low-amplitude wave with a wavelength of 400 nm
(c) High-amplitude wave with a wavelength of 450 nm
(d) Low-amplitude wave with a wavelength of 450 nm
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Textbook Question
The work function of silver metal is 436 kJ/mol. What frequency of light is needed to eject electrons from a sample of silver?
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Textbook Question
Cesium metal is frequently used in photoelectric cells because the amount of energy necessary to eject electrons from a cesium surface is relatively small—only 206.5 kJ/mol. What wavelength of light in nanometers does this correspond to?
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Textbook Question
Sodium-vapor lamps are a common source of lighting. The emission spectrum from this type of lamp is shown. Is this a continuous or line emission spectrum?
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Textbook Question
According to the equation for the Balmer line spectrum of hydrogen, a value of n = 3 gives a red spectral line at 656.3 nm, a value of n = 4 gives a green line at 486.1 nm, and a value of n = 5 gives a blue line at 434.0 nm. Calculate the energy in kilojoules per mole of the radiation corresponding to each of these spectral lines.
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Textbook Question
Calculate the wavelength and energy in kilojoules necessary to completely remove an electron from the second shell (m = 2) of a hydrogen atom (R∞ = 1.097 * 10-2 nm-1).
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